{ "Header": { "BPX": "0.4.0", "Title": "Test case: blended electrode definition with two particle sizes but equivalent chemistry. Compare to nmc_pouch_cell_BPX.json in About:Energy open-source release.", "Model": "DFN" }, "Parameterisation": { "Cell": { "Ambient temperature [K]": 298.15, "Initial temperature [K]": 298.15, "Reference temperature [K]": 298.15, "Lower voltage cut-off [V]": 2.7, "Upper voltage cut-off [V]": 4.2, "Nominal cell capacity [A.h]": 12.5, "Specific heat capacity [J.K-1.kg-1]": 913, "Thermal conductivity [W.m-1.K-1]": 2.04, "Density [kg.m-3]": 1847, "Electrode area [m2]": 0.016808, "Number of electrode pairs connected in parallel to make a cell": 34, "External surface area [m2]": 0.0379, "Volume [m3]": 0.000128 }, "Electrolyte": { "Initial concentration [mol.m-3]": 1000, "Cation transference number": 0.2594, "Conductivity [S.m-1]": "0.1297 * (x / 1000) ** 3 - 2.51 * (x / 1000) ** 1.5 + 3.329 * (x / 1000)", "Diffusivity [m2.s-1]": "8.794e-11 * (x / 1000) ** 2 - 3.972e-10 * (x / 1000) + 4.862e-10", "Conductivity activation energy [J.mol-1]": 17100, "Diffusivity activation energy [J.mol-1]": 17100 }, "Negative electrode": { "Particle radius [m]": 4.12e-06, "Thickness [m]": 5.62e-05, "Diffusivity [m2.s-1]": 2.728e-14, "OCP [V]": "9.47057878e-01 * exp(-1.59418743e+02 * x) - 3.50928033e+04 + 1.64230269e-01 * tanh(-4.55509094e+01 * (x - 3.24116012e-02 )) + 3.69968491e-02 * tanh(-1.96718868e+01 * (x - 1.68334476e-01)) + 1.91517003e+04 * tanh(3.19648312e+00 * (x - 1.85139824e+00)) + 5.42448511e+04 * tanh(-3.19009848e+00 * (x - 2.01660395e+00))", "Entropic change coefficient [V.K-1]": "(-0.1112 * x + 0.02914 + 0.3561 * exp(-((x - 0.08309) ** 2) / 0.004616)) / 1000", "Conductivity [S.m-1]": 0.222, "Surface area per unit volume [m-1]": 499522, "Porosity": 0.253991, "Transport efficiency": 0.128, "Reaction rate constant [mol.m-2.s-1]": 5.199e-06, "Minimum stoichiometry": 0.005504, "Maximum stoichiometry": 0.75668, "Maximum concentration [mol.m-3]": 29730, "Diffusivity activation energy [J.mol-1]": 30000, "Reaction rate constant activation energy [J.mol-1]": 55000 }, "Positive electrode": { "Thickness [m]": 5.23e-05, "Conductivity [S.m-1]": 0.789, "Porosity": 0.277493, "Transport efficiency": 0.1462, "Particle": { "Large Particles": { "Diffusivity [m2.s-1]": 3.2e-14, "Particle radius [m]": 8e-06, "OCP [V]": "-3.04420906 * x + 10.04892207 - 0.65637536 * tanh(-4.02134095 * (x - 0.80063948)) + 4.24678547 * tanh(12.17805062 * (x - 7.57659337)) - 0.3757068 * tanh(59.33067782 * (x - 0.99784492))", "Entropic change coefficient [V.K-1]": -1e-4, "Surface area per unit volume [m-1]": 186331, "Reaction rate constant [mol.m-2.s-1]": 2.305e-05, "Minimum stoichiometry": 0.42424, "Maximum stoichiometry": 0.96210, "Maximum concentration [mol.m-3]": 46200, "Diffusivity activation energy [J.mol-1]": 15000, "Reaction rate constant activation energy [J.mol-1]": 3500 }, "Small Particles": { "Diffusivity [m2.s-1]": 3.2e-14, "Particle radius [m]": 1e-06, "OCP [V]": "-3.04420906 * x + 10.04892207 - 0.65637536 * tanh(-4.02134095 * (x - 0.80063948)) + 4.24678547 * tanh(12.17805062 * (x - 7.57659337)) - 0.3757068 * tanh(59.33067782 * (x - 0.99784492))", "Entropic change coefficient [V.K-1]": -1e-4, "Surface area per unit volume [m-1]": 496883, "Reaction rate constant [mol.m-2.s-1]": 2.305e-05, "Minimum stoichiometry": 0.42424, "Maximum stoichiometry": 0.96210, "Maximum concentration [mol.m-3]": 46200, "Diffusivity activation energy [J.mol-1]": 15000, "Reaction rate constant activation energy [J.mol-1]": 3500 } } }, "Separator": { "Thickness [m]": 2e-05, "Porosity": 0.47, "Transport efficiency": 0.3222 } } }