Validation Log 2024-12-01 07:05:46.770753 mwtab Python Library Version: 1.2.5 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005771/mwtab/json Study ID: ST003515 Analysis ID: AN005771 File format: json Status: Contains Validation Errors Number Errors: 1 Error Log: SCHEMA: Section "CHROMATOGRAPHY" does not match the allowed schema. Wrong key 'SOLVENT_C' in OrderedDict([('CHROMATOGRAPHY_SUMMARY', 'Solvent A: Water; Solvent B: Acetonitrile; Solvent C: 10 mM ammonium acetate in water'), ('INSTRUMENT_NAME', 'Thermo Dionex Ultimate 3000'), ('COLUMN_NAME', 'Higgins Analytical C18 (50 x 2.1mm,2.6um)'), ('COLUMN_TEMPERATURE', '60'), ('FLOW_GRADIENT', 'Mobile phase conditions for the C18 column were 60% A, 35% B, 5% C for 0.5 min, with a linear gradient to 0% A, 95% B, 5% C starting at 1.5 min, and held for 3.5 min, resulting in a 5 min run. The reverse phase column was flushed with 0% A, 95% B, 5% C for 2.5 min, followed by an equilibration solution of 60% A, 35% B, 5% C for the remaining 2.5 min.'), ('FLOW_RATE', 'Flow rate was maintained at 0.4 mL/min for 1.5 min and was then increased to 0.5 mL/min at 2 min and held constant for 3 min'), ('SOLVENT_A', '100% water'), ('SOLVENT_B', '100% acetonitrile'), ('CHROMATOGRAPHY_TYPE', 'Reversed phase'), ('SOLVENT_C', '100% water; 10 mM ammonium acetate')])