Validation Log
2025-03-23 07:29:34.915424
mwtab Python Library Version: 1.2.5
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN005979/mwtab/txt
Study ID:      ST003641
Analysis ID:   AN005979
File format:   txt
Status: Contains Validation Errors
Number Errors: 1

Error Log:
SCHEMA: Section "CHROMATOGRAPHY" does not match the allowed schema. Wrong key 'SOLVENT_C' in OrderedDict([('CHROMATOGRAPHY_SUMMARY', 'Separation and detection of bile acids using a UHPLC gradient method. Duration = 33min. Please see ETV-Lab-Bile-Acids-Methods.pdf for details.'), ('METHODS_FILENAME', 'ETV-Lab-Bile-Acids-Methods.pdf'), ('INSTRUMENT_NAME', 'Thermo Dionex Ultimate 3000'), ('COLUMN_NAME', 'ACE Excel C18-PFP (150 x 2.1mm, 2um, 100Ã\x85)'), ('COLUMN_TEMPERATURE', '50'), ('FLOW_GRADIENT', '0.325 ml/min: 0min: 26% B, 74% A, 5min: 27.5% B, 72.5% A, 14min: 40% B, 60% A, 22min: 85% B, 15% A, 22.1min: 98% B, 2% A, 25.1min 98%, 2% A; 0.2 ml/min: 26min: 100% C, 27.9min: 100% C; 0.3 ml/min: 29min: 28.5% B, 71.5% A; 0.325 ml/min: 30-33min: 28.5% B, 71.5% A'), ('FLOW_RATE', '0.325 mL/min'), ('INJECTION_TEMPERATURE', '5'), ('SOLVENT_A', 'Water 100%; 0.1% formic acid; 10 mM Ammonium acetate'), ('SOLVENT_B', '25% Methanol/75% Acetonitrile; 0.1% formic acid; Ammonium acetate (10mM)'), ('CHROMATOGRAPHY_TYPE', 'Reversed phase'), ('SOLVENT_C', '100% Methanol')])