Validation Log 2025-12-14 20:59:16.966369 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000012/mwtab/txt Study ID: ST000005 Analysis ID: AN000012 File format: txt Status: Contains Validation Issues Number of Issues: 24 Number of Warnings: 9 Number of Value Errors: 16 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected for the subsection, "PHONE", in the "PROJECT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "ADDRESS", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection. Error: The value, "POSITIVE/NEGATIVE", for the subsection, "ION_MODE", in the "MS" section should be one of "Positive", "Negative", "Positive, Negative", or "Unspecified". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "11_14_17-eicosatrienoic acid" "11_14-eicosadienoic acid" "13_16_19-docosatrienoic acid" "13_16-docosadienoic acid" "5_8_11_14_17-eicosapentaenoic acid" "5_8_11-eicosatrienoic acid" "7_10_13_16_19-docosapentaenoic acid" "7Z_10Z_13Z_16Z-docosatetraenoic acid" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "11,14,17-eicosatrienoic acid" "11,14-eicosadienoic acid" "13,16,19-docosatrienoic acid" "13,16-docosadienoic acid" "5,8,11,14,17-eicosapentaenoic acid" "5,8,11-eicosatrienoic acid" "7,10,13,16,19-docosapentaenoic acid" "7Z,10Z,13Z,16Z-docosatetraenoic acid" Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the METABOLITES table has all null values. Warning: The "ri" column at position 3 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 4 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values. Warning: The "other_id" column at position 8 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 9 in the METABOLITES table has all null values.