Validation Log
2025-12-14 20:59:36.536469
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000025/mwtab/json
Study ID:      ST000010
Analysis ID:   AN000025
File format:   json
Status: Contains Validation Issues
Number of Issues: 25

Number of Warnings: 7

Number of Value Errors: 17

Number of Consistency Errors: 2

Number of Format Errors: 5

Issue Log:
Error: An empty value or a null value was detected in ["PROJECT"]["ADDRESS"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["PROJECT"]["PHONE"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["STUDY"]["ADDRESS"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["STUDY"]["PHONE"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["COLLECTION"]["COLLECTION_SUMMARY"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLEPREP_SUMMARY"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["MS"]["MS_COMMENTS"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["CHROMATOGRAPHY_TYPE"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["INSTRUMENT_NAME"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["COLUMN_NAME"]. A legitimate value should be provided for this required key.
Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing.
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"2^_4^-DIHYDROXYACETOPHENONE"
	"2^-DEOXYADENOSINE 5^-MONOPHOSPHATE"
	"2^-DEOXYCYTIDINE"
	"2^-DEOXYCYTIDINE 5^-MONOPHOSPHATE"
	"2^-DEOXYGUANOSINE 5^-DIPHOSPHATE"
	"3_5-DIIODO-L-TYROSINE"
	"3^-CMP"
	"5ALPHA-PREGNANE-3_20-DIONE"
	"6_7-DIHYDROBIOPTERIN"
	"ADENOSINE 3^_5^-CYCLIC MONOPHOSPHATE"
	"ADENOSINE 5^-MONOPHOSPHATE"
	"CITRATE_1"
	"CORTISOL 21-ACETATE_1"
	"CYCLOHEXANE-1_3-DIONE"
	"CYSTINE_1"
	"CYTIDINE 2`_3`-CYCLIC MONOPHOSPHATE (CCMP)"
	"CYTIDINE 5^-DIPHOSPHOCHOLINE"
	"DIHYDROFOLATE_1"
	"DOCOSAHEXAENOIC ACID_1"
	"DOCOSAHEXAENOYLGLYCEROPHOSPHOCHOLINE_1"
	"FOLIC ACID_1"
	"FRUCTOSE 1_6-BIPHOSPHATE"
	"GLUTAMINE_1"
	"GLUTATHIONE OXIDIZED_1"
	"GUANOSINE 3`_5`-CYCLIC MONOPHOSPHATE"
	"GUANOSINE 5^ MONOPHOSPHATE"
	"INOSINE 5^-MONOPHOSPHATE"
	"LL-2_6-DIAMINOHEPTANEDIOATE"
	"METHYL JASMONATE_1"
	"MYRISTOYLGLYCEROPHOSPHOCHOLINE_1"
	"N-ACETYL-L-ASPARTIC ACID_1"
	"N-CYCLOHEXYLFORMAMIDE_1"
	"RIBULOSE 1_5-BISPHOSPHATE"
	"S-ADENOSYL-L-HOMOCYSTEINE_1"
	"SUCCINATE_1"
	"TRANS-CYCLOHEXANE-1_2-DIOL"
	"UREA_1"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"2',4'-DIHYDROXYACETOPHENONE"
	"2'-DEOXYADENOSINE 5'-MONOPHOSPHATE"
	"2'-DEOXYCYTIDINE"
	"2'-DEOXYCYTIDINE 5'-MONOPHOSPHATE"
	"2'-DEOXYGUANOSINE 5'-DIPHOSPHATE"
	"3'-CMP"
	"ADENOSINE 3',5'-CYCLIC MONOPHOSPHATE"
	"ADENOSINE 5'-MONOPHOSPHATE"
	"CITRATE_2"
	"CORTISOL 21-ACETATE_2"
	"CYSTINE_2"
	"CYTIDINE 2`,3`-CYCLIC MONOPHOSPHATE (CCMP)"
	"CYTIDINE 5'-DIPHOSPHOCHOLINE"
	"DIHYDROFOLATE_2"
	"DOCOSAHEXAENOIC ACID_2"
	"DOCOSAHEXAENOYLGLYCEROPHOSPHOCHOLINE_2"
	"FOLIC ACID_2"
	"GLUTAMINE_2"
	"GLUTATHIONE OXIDIZED_2"
	"GUANOSINE 3`,5`-CYCLIC MONOPHOSPHATE"
	"GUANOSINE 5' MONOPHOSPHATE"
	"INOSINE 5'-MONOPHOSPHATE"
	"METHYL JASMONATE_2"
	"MYRISTOYLGLYCEROPHOSPHOCHOLINE_2"
	"N-ACETYL-L-ASPARTIC ACID_2"
	"N-CYCLOHEXYLFORMAMIDE_2"
	"S-ADENOSYL-L-HOMOCYSTEINE_2"
	"SUCCINATE_2"
	"UREA_2"
Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "moverz_quant" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "inchi_key" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.