Validation Log 2025-12-14 21:00:07.823703 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000034/mwtab/txt Study ID: ST000017 Analysis ID: AN000034 File format: txt Status: Contains Validation Issues Number of Issues: 15 Number of Warnings: 7 Number of Value Errors: 12 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected for the subsection, "ADDRESS", in the "PROJECT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "ADDRESS", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection. Error: The value, "3500V", for the subsection, "CAPILLARY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "40C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE" "1_2-DIPALMITOYL-SN-GLYCEROL" "2^_4^-DIHYDROXYACETOPHENONE" "2_4-DIHYDROXYPTERIDINE" "2_5-DIMETHYLPYRAZINE" "2_6-DIHYDROXYPYRIDINE" "2^-DEOXYADENOSINE" "2^-DEOXYADENOSINE 5^-MONOPHOSPHATE" "2^-DEOXYCYTIDINE" "2^-DEOXYCYTIDINE 5^-MONOPHOSPHATE" "2^-DEOXYGUANOSINE 5^-DIPHOSPHATE" "2-HYDROXYBUTYRIC ACID_1" "3_3^_5-TRIIODO-L-THYRONINE" "3_3^-DITHIODIVALINE" "3_4-DICHLOROANILINE" "3_4-DIHYDROXYBENZOATE" "3_4-DIHYDROXY-L-PHENYLALANINE" "3_4-DIHYDROXYPHENYLACETATE" "3-ALPHA_11-BETA_17-ALPHA_21-TETRAHYDROXY- 5-ALPHA-PREGNAN-20-ONE" "3^-CMP" "3-(CYSTEIN-S-YL)ACETAMINOPHEN_1" "3^-DEPHOSPHO COA" "5^-DEOXYADENOSINE" "5-METHYLCYTOSINE_1" "6_7-DIHYDROBIOPTERIN" "ADENOSINE 2^_3^-CYCLIC MONOPHOSPHATE" "ADENOSINE 5^-MONOPHOSPHATE" "ALPHA-KETO-GLUTARATE_1" "CHOLESTA-5_7-DIEN-3BETA-OL" "CORTISOL 21-ACETATE_1" "CYCLOHEXANE-1_3-DIONE" "CYS-GLY_ OXIDIZED" "CYSTINE_1" "CYTIDINE 5^-DIPHOSPHOCHOLINE" "D-GLUCONO-1_5-LACTONE" "DIHYDROFOLATE_1" "DIMETHYL MALEATE_1" "DOCOSAHEXAENOYLGLYCEROPHOSPHOCHOLINE_1" "ENKEPHALINE_ (D-ALA)2-LEU" "FRUCTOSE 1_6-BIPHOSPHATE" "GLUTAMINE_1" "GLUTATHIONE OXIDIZED_1" "GUANOSINE 3`_5`-CYCLIC MONOPHOSPHATE" "GUANOSINE 5^-DIPHOSPHATE" "GUANOSINE 5^ MONOPHOSPHATE" "INOSINE 5^-DIPHOSPHATE" "INOSINE 5^-MONOPHOSPHATE" "LL-2_6-DIAMINOHEPTANEDIOATE" "METHYL JASMONATE_1" "MYRISTOYLGLYCEROPHOSPHOCHOLINE_1" "N-ACETYL-DL-METHIONINE_1" "N-ACETYL-L-ASPARTIC ACID_1" "N-CYCLOHEXYLFORMAMIDE_1" "N_N-DIMETHYL-1_4-PHENYLENEDIAMINE" "N_N_N-TRIMETHYLLYSINE" "OROTIDINE 5^-MONOPHOSPHATE" "POSSIBLY C42H80NO7P_ Na ADDUCT" "PROMETRYN_1" "RIBULOSE 1_5-BISPHOSPHATE" "S-ADENOSYL-L-HOMOCYSTEINE_1" "SUCCINATE_1" "TRANS-CYCLOHEXANE-1_2-DIOL" "URATE_1" "UREA_1" "URIDINE 5^-DIPHOSPHO-N-ACETYLGALACTOSAMINE" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "2',4'-DIHYDROXYACETOPHENONE" "2'-DEOXYADENOSINE" "2'-DEOXYADENOSINE 5'-MONOPHOSPHATE" "2'-DEOXYCYTIDINE" "2'-DEOXYCYTIDINE 5'-MONOPHOSPHATE" "2'-DEOXYGUANOSINE 5'-DIPHOSPHATE" "2-HYDROXYBUTYRIC ACID_2" "3,3',5-TRIIODO-L-THYRONINE" "3,3'-DITHIODIVALINE" "3'-CMP" "3-(CYSTEIN-S-YL)ACETAMINOPHEN_2" "3'-DEPHOSPHO COA" "5'-DEOXYADENOSINE" "5-METHYLCYTOSINE_2" "ADENOSINE 2',3'-CYCLIC MONOPHOSPHATE" "ADENOSINE 5'-MONOPHOSPHATE" "ALPHA-KETO-GLUTARATE_2" "CORTISOL 21-ACETATE_2" "CYSTINE_2" "CYTIDINE 5'-DIPHOSPHOCHOLINE" "DIHYDROFOLATE_2" "DIMETHYL MALEATE_2" "DOCOSAHEXAENOYLGLYCEROPHOSPHOCHOLINE_2" "GLUTAMINE_2" "GLUTATHIONE OXIDIZED_2" "GUANOSINE 5'-DIPHOSPHATE" "GUANOSINE 5' MONOPHOSPHATE" "INOSINE 5'-DIPHOSPHATE" "INOSINE 5'-MONOPHOSPHATE" "METHYL JASMONATE_2" "MYRISTOYLGLYCEROPHOSPHOCHOLINE_2" "N-ACETYL-DL-METHIONINE_2" "N-ACETYL-L-ASPARTIC ACID_2" "N-CYCLOHEXYLFORMAMIDE_2" "OROTIDINE 5'-MONOPHOSPHATE" "PROMETRYN_2" "S-ADENOSYL-L-HOMOCYSTEINE_2" "SUCCINATE_2" "URATE_2" "UREA_2" "URIDINE 5'-DIPHOSPHO-N-ACETYLGALACTOSAMINE" Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the METABOLITES table has all null values. Warning: The "ri" column at position 3 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 4 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.