Validation Log 2025-12-14 21:01:20.456004 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000064/mwtab/txt Study ID: ST000042 Analysis ID: AN000064 File format: txt Status: Contains Validation Issues Number of Issues: 19 Number of Warnings: 7 Number of Value Errors: 11 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "10-HYDROXYDECANOATE_1" "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE" "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE_1" "1_2-DIPALMITOYL-SN-GLYCEROL" "2`_4`-DIHYDROXYACETOPHENONE" "2_6-DIHYDROXYPYRIDINE" "2`-DEOXYGUANOSINE_1" "3_4-DIHYDROXYBENZOATE" "3_4-DIHYDROXYPHENYLACETATE" "3_5-DIIODO-L-THYRONINE" "3_5-DIIODO-L-THYRONINE_1" "3_5-DIIODO-L-TYROSINE" "3_5-DIIODO-L-TYROSINE_1" "3-ALPHA_11-BETA_17-ALPHA_21-TETRAHYDROXY- 5-ALPHA-PREGNAN-20-ONE" "4-METHYL-2-OXOPENTANOATE_1" "AZELAIC ACID_1" "BILIVERDIN_1" "BIOTIN_1" "BIS(2-ETHYLHEXYL)PHTHALATE_1" "BOC-ALA-OH_1" "BOC-LYS-OH_1" "BUTYRYLCARNITINE (*)_1" "C-GLYCOSYLTRYPTOPHAN (*)_1" "CHOLESTA-5_7-DIEN-3BETA-OL" "CIS-7_10_13_16-DOCOSATETRAENOIC ACID" "CORTICOSTERONE_1" "CORTISOL_1" "CORTISOL 21-ACETATE_1" "CORTISONE_1" "CYCLOHEXANE-1_3-DIONE" "CYCLOHEXANE-1_3-DIONE_1" "DEOXYCHOLATE_1" "DEOXYCORTICOSTERONE_1" "DEOXYURIDINE_1" "DETHIOBIOTIN_1" "DIMETHYL MALEATE_1" "DOCOSAHEXAENOIC ACID_1" "EDTA (*)_1" "ETHYL 4-OXOCYCLOHEXANECARBOXYLATE_1" "FERULATE_1" "GLUTAMINE_1" "HIPPURATE_1" "HYPOXANTHINE_1" "INOSINE_1" "LINOLEOYLGLYCEROPHOSPHOCHOLINE (*)_1" "LL-2_6-DIAMINOHEPTANEDIOATE" "LUMICHROME_1" "MELATONIN_1" "METHYL JASMONATE_1" "N1-METHYL-2-PYRIDONE-5-CARBOXAMIDE (*)_1" "N6-(DELTA2-ISOPENTENYL)-ADENINE_1" "N-ACETYL-L-ALANINE_1" "N-ACETYL-L-CYSTEINE_1" "N-ACETYL-L-PHENYLALANINE_1" "N-ACETYLSEROTONIN_1" "N-CYCLOHEXYLFORMAMIDE_1" "N_N_N-TRIMETHYLLYSINE" "OLEAMIDE_1" "ORNITHINE_1" "PALMITOLEOYLGLYCEROPHOSPHOCHOLINE (*)_1" "PALMITOYLGLYCEROPHOSPHOCHOLINE (*)_1" "PANTOLACTONE_1" "PHENYLALANINE_1" "PROGESTERONE_1" "PROMETRYN_1" "RETINAL_1" "SUBERIC ACID_1" "TAURINE_1" "TRANS-CYCLOHEXANE-1_2-DIOL" "TRYPTOPHAN_1" "TRYPTOPHAN BETAINE (*)_1" "UREA_1" "URIDINE_1" "VALINE_1" "VALINE (*)_1" "VITAMIN D3_1" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "10-HYDROXYDECANOATE_3" "2`-DEOXYGUANOSINE_2" "4-METHYL-2-OXOPENTANOATE_2" "AZELAIC ACID_2" "BILIVERDIN_3" "BIOTIN_3" "BIS(2-ETHYLHEXYL)PHTHALATE_3" "BOC-ALA-OH_2" "BOC-LYS-OH_2" "BUTYRYLCARNITINE (*)_2" "C-GLYCOSYLTRYPTOPHAN (*)_2" "CORTICOSTERONE_2" "CORTISOL_2" "CORTISOL 21-ACETATE_3" "CORTISONE_2" "DEOXYCHOLATE_2" "DEOXYCORTICOSTERONE_2" "DEOXYURIDINE_2" "DETHIOBIOTIN_2" "DIMETHYL MALEATE_2" "DOCOSAHEXAENOIC ACID_2" "EDTA (*)_2" "ETHYL 4-OXOCYCLOHEXANECARBOXYLATE_2" "FERULATE_2" "GLUTAMINE_2" "HIPPURATE_2" "HYPOXANTHINE_2" "INOSINE_2" "LINOLEOYLGLYCEROPHOSPHOCHOLINE (*)_3" "LUMICHROME_2" "MELATONIN_3" "METHYL JASMONATE_2" "N1-METHYL-2-PYRIDONE-5-CARBOXAMIDE (*)_3" "N6-(DELTA2-ISOPENTENYL)-ADENINE_2" "N-ACETYL-L-ALANINE_2" "N-ACETYL-L-CYSTEINE_2" "N-ACETYL-L-PHENYLALANINE_2" "N-ACETYLSEROTONIN_2" "N-CYCLOHEXYLFORMAMIDE_3" "OLEAMIDE_2" "ORNITHINE_2" "PALMITOLEOYLGLYCEROPHOSPHOCHOLINE (*)_2" "PALMITOYLGLYCEROPHOSPHOCHOLINE (*)_3" "PANTOLACTONE_2" "PHENYLALANINE_2" "PROGESTERONE_2" "PROMETRYN_2" "RETINAL_2" "SUBERIC ACID_2" "TAURINE_2" "TRYPTOPHAN_2" "TRYPTOPHAN BETAINE (*)_4" "UREA_2" "URIDINE_3" "VALINE_2" "VALINE (*)_2" "VITAMIN D3_2" Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the METABOLITES table has all null values. Warning: The "ri" column at position 3 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 4 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.