Validation Log 2025-12-14 21:02:06.216308 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000079/mwtab/json Study ID: ST000046 Analysis ID: AN000079 File format: json Status: Contains Validation Issues Number of Issues: 18 Number of Warnings: 8 Number of Value Errors: 9 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected in ["STUDY"]["ADDRESS"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["STUDY"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "10_11-epoxy-chlorovuloneI" "11-deoxy-16_16-dimethyl-PGE2" "12alpha-Hydroxy-3-oxochola-4_6-dien-24-oicAcid" "1_2-di-(9Z-octadecenoyl)-sn-glycero-3-phospho-(1^-myo-inositol)" "1_2-Didecanoyl-glycerol(10:0)" "13_14-dihydro-15-keto-PGF2alpha" "1_3-Dimethyluricacid" "13E_17-octadecadienoicacid" "13S-hydroxy-9E_11Z-octadecadienoicacid" "16a-Hydroxyprednisolone16_17-acetonide" "16-hydroperoxy-9Z_12_14E-octadecatrienoicacid" "17-alpha_21-dihydroxy-11_20-dioxo-5-beta-pregnan-3-alpha-yl-beta-d-glucuronide" "1alpha_25-Dihydroxy-2-[3^-(methoxymethoxy)propylidene]-19-norvitaminD3" "1alpha_25-dihydroxy-24-oxovitaminD_3/1alpha_25-dihydroxy-24-oxocholecalciferol" "1alpha_25-dihydroxy-26_27-dimethyl-22-oxavitaminD3/1alpha_25-dihydroxy-26_27-dimethyl-22-oxachole" "1alpha_25-dihydroxy-2beta-(5-hydroxypentoxy)vitaminD3/1alpha_25-dihydroxy-2beta-(5-hydroxypentoxy" "1alpha_25-dihydroxy-2beta-butoxyvitaminD3/1alpha_25-dihydroxy-2beta-butoxycholecalciferol" "1alpha_2beta_25-trihydroxy-19-norvitaminD3/1alpha_2beta_25-trihydroxy-19-norcholecalciferol" "1alpha-hydroxy-18-[m-(1-hydroxy-1-ethylpropyl)-benzyloxy]-23_24_25_26_27-pentanorvitaminD3/1alpha" "1-Fluoro-25-hydroxy-16-ene-23-yne-26_27-hexadeuterovitamin-D3" "1-heneicosanoyl-2-(4Z_7Z_10Z_13Z_16Z_19Z-docosahexaenoyl)-sn-glycero-3-phosphoethanolamine" "1-O-(1Z-hexadecenyl)-2-(4Z_7Z_10Z_13Z_16Z_19Z-docosahexaenoyl)-sn-glycero-3-phosphoethanolamine" "(20S)-1alpha_20_25-trihydroxyvitaminD_3/(20S)-1alpha_20_25-trihydroxycholecalciferol" "(22S)-1alpha_22_25-trihydroxy-23_24-tetradehydro-24a_24b-dihomo-20-epivitaminD3/(22S)-1alpha_22_2" "2_3-DIACETOXY-7_8-EPOXY-24_29-DINOR-1_3_5-FRIEDELATRIENE-20-CARBOXYLICACID" "2_3-Dichloro-4-(a-hydroxy-2-thenyl)phenoxyaceticacid" "2_3-Dihydroxy-3-methylvalericacid" "2_3-Dihydroxybenzoicacid" "2_3-Dihydroxybenzoicacid-0.9889191" "2_3-Naphthalenedicarboxylicacid" "2_3-Naphthalenedicarboxylicacid-2.6398537" "(23S)-1alpha_23_25-trihydroxy-24-oxovitaminD3/(23S)-1alpha_23_25-trihydroxy-24-oxocholecalciferol" "(23S_25R)-25-hydroxyvitaminD326_23-lactone/(23S_25R)-25-hydroxycholecalciferol26_23-lactone" "24_24-Difluoro-25-hydroxy-26_27-dimethylvitaminD3" "2_4-DICHLOROPHENOXYACETICACID" "2_4-DICHLOROPHENOXYACETICACID_ISOOCTYLESTER" "2_4-DICHLOROPHENOXYBUTYRICACID_METHYLESTER" "2_4-DINITROPHENOL" "(24R)-1alpha_24_25_26-tetrahydroxyvitaminD2/(24R)-1alpha_24_25_26-tetrahydroxyergocalciferol" "(24R)-1alpha_24_25-trihydroxyvitaminD2/(24R)-1alpha_24_25-trihydroxyergocalciferol" "2_5-Dimethoxycinnamicacid" "25-Hydroxy[26_27-methyl]vitaminD33beta-(1_2-epoxypropyl)ether" "27-nor-5b-cholestane-3a_7a_12a_24_25-pentol" "2beta_3beta-Dihydroxy-6-oxo-5alpha-chol-7-en-24-oicAcid" "2-Naphthaleneaceticacid_6-hydroxy-" "2-Naphthaleneaceticacid_6-hydroxy--2.938551" "3_16-DIDEOXYMEXICANOLIDE-3alpha-DIOL" "3_6_8-dodecatrien-1-ol" "3_7_12-Trioxochola-1_5-dien-24-oicAcid" "3_9_15-Docosatriynoicacid" "3_9_15-Docosatriynoicacid-1.0828342" "3-ACETOXYPREGN-16-EN-12_20-DIONE" "3alpha_6alpha_7alpha_12alpha-Tetrahydroxy-5beta-cholest-24-en-26-oicacid" "3alpha_7alpha_12alpha_24-tetrahydroxy-24-methyl-5beta-cholestan-26-oicacid" "3alpha_7alpha_12alpha-Trihydroxy-24-methyl-5beta-cholest-23-en-26-oicacid" "3beta_4beta-Dihydroxy-5beta-cholan-24-oicAcid" "3beta_6alpha_7beta-Trihydroxy-5beta-cholan-24-oicAcid" "3beta_7beta-Dihydroxy-12-oxo-5beta-cholan-24-oicAcid" "3beta-ACETOXYDEOXYANGOLENSICACID_METHYLESTER" "3D_7D_11D-Phytanicacid" "3-Hydroxy-2-methyl-[R-(R_S)]-butanoicacid" "3-Hydroxy-2-methyl-[R-(R_S)]-butanoicacid-1.497357" "4_7_10_13_16-docosapentaenoicacid" "4_8-dimethyl-dodecanoicacid" "4_8-dimethyl-dodecanoicacid-1.9773146" "_4-Dimethoxyphenethylamine" "4Z_7Z_10Z_13Z-eicosatetraenoicacid" "5-[2-(hydroxymethyl)-5-methylphenoxy]-2_2-dimethyl-Pentanoicacid(GemfibrozilM4)" "5-[2-(hydroxymethyl)-5-methylphenoxy]-2_2-dimethyl-Pentanoicacid(GemfibrozilM4)-1.9758611" "5-(4-hydroxy-2_5-dimethylphenoxy)-2_2-dimethyl-Pentanoicacid(GemfibrozilM1)" "5-(4-hydroxy-2_5-dimethylphenoxy)-2_2-dimethyl-Pentanoicacid(GemfibrozilM1)-1.2524415" "5_6-Dihydrouridine" "5_7-nonadienoicacid" "5_8-Dihydroxy-3_4-dihydrocarbostyril" "5&946;-CHOLANICACID-3&945;_12&945;-DIOLN-(2-SULPHOETHYL)-AMIDE" "5&946;-CHOLANICACID-3&945;_12&945;-DIOLN-(2-SULPHOETHYL)-AMIDE-3.2472885" "(5E_10E)-19-(3-carboxylpropyl)vitaminD3/(5E_10E)-19-(3-carboxylpropyl)cholecalciferol" "(5E_10Z)-19-fluoro-1alpha-hydroxyvitamin-D3/(5E_10Z)-19-fluoro-1alpha-hydroxycholecalciferol" "(6S)-1alpha_25-dihydroxyvitaminD36_19-sulfurdioxideadduct/(6S)-1alpha_25-dihydroxycholecalcife" "7alpha-Hydroxy-3_12-dioxochola-1_4-dien-24-oicAcid" "9_12_14-octadecatrienoicacid" "9_12-dioxo-dodecanoicacid" "9_12-dioxo-dodecanoicacid-1.2552382" "9_13-dihydroxy-11-octadecenoicacid" "ABSCISICACID(cis_trans)" "ANGOLENSICACID_METHYLESTER" "Benzenemethanol_2-(2-aminopropoxy)-3-methyl-" "Benzenemethanol_2-(2-aminopropoxy)-3-methyl--1.2709796" "Erythrono-1_4-lactone" "Glc-GP(18:0/20:4(5Z_8Z_11Z_14Z))" "Glutathione_oxidized" "GPEtn(16:0/18:2(9Z_12Z))" "GPEtn(16:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))" "GPEtn(18:0/18:3(9Z_12Z_15Z))[U]" "GPEtn(18:0/20:4(5Z_8Z_11Z_14Z))[U]" "GPEtn(18:0/20:4(5Z_8Z_11Z_14Z))[U]-5.053175" "GPEtn(18:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))" "GPEtn(18:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))-4.432728" "GPEtn(O-16:0/22:5(4Z_7Z_10Z_13Z_16Z))" "GPEtn(O-16:0/22:5(4Z_7Z_10Z_13Z_16Z))-4.396363" "GPGro(17:0/20:4(5Z_8Z_11Z_14Z))" "GPSer(18:0/20:4(5Z_8Z_11Z_14Z))" "GPSer(18:0/22:6(4Z_7Z_10Z_13Z_16Z_19Z))" "Limonene-1_2-epoxide" "QUERCETINTETRAMETHYL(5_7_3^_4^)ETHER" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "10,11-epoxy-chlorovuloneI" "12alpha-Hydroxy-3-oxochola-4,6-dien-24-oicAcid" "1,2-Didecanoyl-glycerol(10:0)" "1,3-Dimethyluricacid" "13E,17-octadecadienoicacid" "13S-hydroxy-9E,11Z-octadecadienoicacid" "16a-Hydroxyprednisolone16,17-acetonide" "16-hydroperoxy-9Z,12,14E-octadecatrienoicacid" "17-alpha,21-dihydroxy-11,20-dioxo-5-beta-pregnan-3-alpha-yl-beta-d-glucuronide" "1alpha,25-Dihydroxy-2-[3'-(methoxymethoxy)propylidene]-19-norvitaminD3" "1alpha,25-dihydroxy-24-oxovitaminD_3/1alpha,25-dihydroxy-24-oxocholecalciferol" "1alpha,25-dihydroxy-26,27-dimethyl-22-oxavitaminD3/1alpha,25-dihydroxy-26,27-dimethyl-22-oxachole" "1alpha,25-dihydroxy-2beta-(5-hydroxypentoxy)vitaminD3/1alpha,25-dihydroxy-2beta-(5-hydroxypentoxy" "1alpha,25-dihydroxy-2beta-butoxyvitaminD3/1alpha,25-dihydroxy-2beta-butoxycholecalciferol" "1alpha,2beta,25-trihydroxy-19-norvitaminD3/1alpha,2beta,25-trihydroxy-19-norcholecalciferol" "1alpha-hydroxy-18-[m-(1-hydroxy-1-ethylpropyl)-benzyloxy]-23,24,25,26,27-pentanorvitaminD3/1alpha" "(20S)-1alpha,20,25-trihydroxyvitaminD_3/(20S)-1alpha,20,25-trihydroxycholecalciferol" "(22S)-1alpha,22,25-trihydroxy-23,24-tetradehydro-24a,24b-dihomo-20-epivitaminD3/(22S)-1alpha,22,2" "2,3-DIACETOXY-7,8-EPOXY-24,29-DINOR-1,3,5-FRIEDELATRIENE-20-CARBOXYLICACID" "2,3-Dichloro-4-(a-hydroxy-2-thenyl)phenoxyaceticacid" "2,3-Dihydroxy-3-methylvalericacid" "2,3-Dihydroxybenzoicacid" "2,3-Dihydroxybenzoicacid-0.9889191" "2,3-Naphthalenedicarboxylicacid" "2,3-Naphthalenedicarboxylicacid-2.6398537" "(23S)-1alpha,23,25-trihydroxy-24-oxovitaminD3/(23S)-1alpha,23,25-trihydroxy-24-oxocholecalciferol" "(23S,25R)-25-hydroxyvitaminD326,23-lactone/(23S,25R)-25-hydroxycholecalciferol26,23-lactone" "24,24-Difluoro-25-hydroxy-26,27-dimethylvitaminD3" "2,4-DICHLOROPHENOXYACETICACID" "2,4-DICHLOROPHENOXYACETICACID,ISOOCTYLESTER" "2,4-DICHLOROPHENOXYBUTYRICACID,METHYLESTER" "(24R)-1alpha,24,25,26-tetrahydroxyvitaminD2/(24R)-1alpha,24,25,26-tetrahydroxyergocalciferol" "(24R)-1alpha,24,25-trihydroxyvitaminD2/(24R)-1alpha,24,25-trihydroxyergocalciferol" "2,5-Dimethoxycinnamicacid" "25-Hydroxy[26,27-methyl]vitaminD33beta-(1,2-epoxypropyl)ether" "2beta,3beta-Dihydroxy-6-oxo-5alpha-chol-7-en-24-oicAcid" "2-Naphthaleneaceticacid,6-hydroxy-" "2-Naphthaleneaceticacid,6-hydroxy--2.938551" "3,7,12-Trioxochola-1,5-dien-24-oicAcid" "3,9,15-Docosatriynoicacid" "3,9,15-Docosatriynoicacid-1.0828342" "3alpha,6alpha,7alpha,12alpha-Tetrahydroxy-5beta-cholest-24-en-26-oicacid" "3alpha,7alpha,12alpha,24-tetrahydroxy-24-methyl-5beta-cholestan-26-oicacid" "3alpha,7alpha,12alpha-Trihydroxy-24-methyl-5beta-cholest-23-en-26-oicacid" "3beta,4beta-Dihydroxy-5beta-cholan-24-oicAcid" "3beta,6alpha,7beta-Trihydroxy-5beta-cholan-24-oicAcid" "3beta,7beta-Dihydroxy-12-oxo-5beta-cholan-24-oicAcid" "3beta-ACETOXYDEOXYANGOLENSICACID,METHYLESTER" "3D,7D,11D-Phytanicacid" "3-Hydroxy-2-methyl-[R-(R,S)]-butanoicacid" "3-Hydroxy-2-methyl-[R-(R,S)]-butanoicacid-1.497357" "4,7,10,13,16-docosapentaenoicacid" "4,8-dimethyl-dodecanoicacid" "4,8-dimethyl-dodecanoicacid-1.9773146" "4Z,7Z,10Z,13Z-eicosatetraenoicacid" "5-[2-(hydroxymethyl)-5-methylphenoxy]-2,2-dimethyl-Pentanoicacid(GemfibrozilM4)" "5-[2-(hydroxymethyl)-5-methylphenoxy]-2,2-dimethyl-Pentanoicacid(GemfibrozilM4)-1.9758611" "5-(4-hydroxy-2,5-dimethylphenoxy)-2,2-dimethyl-Pentanoicacid(GemfibrozilM1)" "5-(4-hydroxy-2,5-dimethylphenoxy)-2,2-dimethyl-Pentanoicacid(GemfibrozilM1)-1.2524415" "5,7-nonadienoicacid" "5&946;-CHOLANICACID-3&945;,12&945;-DIOLN-(2-SULPHOETHYL)-AMIDE" "5&946;-CHOLANICACID-3&945;,12&945;-DIOLN-(2-SULPHOETHYL)-AMIDE-3.2472885" "(5E,10E)-19-(3-carboxylpropyl)vitaminD3/(5E,10E)-19-(3-carboxylpropyl)cholecalciferol" "(5E,10Z)-19-fluoro-1alpha-hydroxyvitamin-D3/(5E,10Z)-19-fluoro-1alpha-hydroxycholecalciferol" "(6S)-1alpha,25-dihydroxyvitaminD36,19-sulfurdioxideadduct/(6S)-1alpha,25-dihydroxycholecalcife" "7alpha-Hydroxy-3,12-dioxochola-1,4-dien-24-oicAcid" "9,12,14-octadecatrienoicacid" "9,12-dioxo-dodecanoicacid" "9,12-dioxo-dodecanoicacid-1.2552382" "9,13-dihydroxy-11-octadecenoicacid" "ABSCISICACID(cis,trans)" "ANGOLENSICACID,METHYLESTER" "Benzenemethanol,2-(2-aminopropoxy)-3-methyl-" "Benzenemethanol,2-(2-aminopropoxy)-3-methyl--1.2709796" "Glutathione,oxidized" "GPEtn(18:0/20:4(5Z,8Z,11Z,14Z))[U]-5.053175" "GPEtn(18:0/22:6(4Z,7Z,10Z,13Z,16Z,19Z))-4.432728" "GPEtn(O-16:0/22:5(4Z,7Z,10Z,13Z,16Z))-4.396363" "QUERCETINTETRAMETHYL(5,7,3',4')ETHER" Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "inchi_key" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.