Validation Log
2025-12-14 21:02:23.052701
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000083/mwtab/txt
Study ID:      ST000047
Analysis ID:   AN000083
File format:   txt
Status: Contains Validation Issues
Number of Issues: 16

Number of Warnings: 6

Number of Value Errors: 8

Number of Consistency Errors: 2

Number of Format Errors: 5

Issue Log:
Error: An empty value or a null value was detected for the subsection, "ADDRESS", in the "STUDY" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection.
Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section  is missing.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"13-ethyl-2_17-dihydroxy-18_19-Dinorpregna-4_9_11-trien-20-yn-3-one"
	"1_3-Glyceryldinitrate"
	"1alpha_25-dihydroxy-24-oxovitaminD_3/1alpha_25-dihydroxy-24-oxocholecalciferol"
	"1beta_25-dihydroxy-3-deoxy-3-thiavitaminD3/1beta_25-dihydroxy-3-deoxy-3-thiacholecalciferol"
	"(22E_24E)-1alpha_25-dihydroxy-22_23_24_24a-tetradehydro-24a-homovitaminD3/(22E_24E)-1alpha_25-dih"
	"(22R)-1alpha_22_25-trihydroxy-23_24-tetradehydro-24a_24b-dihomo-20-epivitaminD3/(22R)-1alpha_22_2"
	"2_3-Dihydroxy-3-methylvalericacid"
	"2_3-Dioxogulonicacid"
	"2_4-DINITROPHENOL"
	"2_5-Dimethoxycinnamicacid"
	"2^-Deoxyuridine5^-diphosphate(dUDP)"
	"2H-1-Benzopyran-6-aceticacid_7-hydroxy-8-methoxy-2-oxo-"
	"2-Heptenedioicacid_4-oxo-"
	"2-Naphthaleneaceticacid_6-hydroxy-"
	"2-Naphthaleneaceticacid_6-hydroxy--3.1083467"
	"2-Naphthaleneaceticacid_6-hydroxy--3.220013"
	"3_4_5-Trihydroxystilbene"
	"3D_7D_11D-Phytanicacid"
	"3E_5E-tridecadienoicacid"
	"3-Hydroxy-2-methyl-[R-(R_S)]-butanoicacid"
	"4_8-dimethyl-dodecanoicacid"
	"5-[2-(hydroxymethyl)-5-methylphenoxy]-2_2-dimethyl-Pentanoicacid(GemfibrozilM4)"
	"5-(4-hydroxy-2_5-dimethylphenoxy)-2_2-dimethyl-Pentanoicacid(GemfibrozilM1)"
	"5_6-Dihydrouridine"
	"6b_11b_16a_17a_21-Pentahydroxypregna-1_4-diene-3_20-dione16_17-acetonide"
	"6b_11b_16a_17a_21-Pentahydroxypregna-1_4-diene-3_20-dione16_17-acetonide-1.9632031"
	"Benzaldehyde_p-amino-_thiosemicarbazone"
	"(+)-Bornane-2_5-dione"
	"Erythrono-1_4-lactone"
	"N_N-HEXAMETHYLENEAMILORIDE"
	"Propanoicacid_2-hydroxy-3-[(4-hydroxy-1-naphthalenyl)oxy]-"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"1,3-Glyceryldinitrate"
	"1alpha,25-dihydroxy-24-oxovitaminD_3/1alpha,25-dihydroxy-24-oxocholecalciferol"
	"1beta,25-dihydroxy-3-deoxy-3-thiavitaminD3/1beta,25-dihydroxy-3-deoxy-3-thiacholecalciferol"
	"(22E,24E)-1alpha,25-dihydroxy-22,23,24,24a-tetradehydro-24a-homovitaminD3/(22E,24E)-1alpha,25-dih"
	"(22R)-1alpha,22,25-trihydroxy-23,24-tetradehydro-24a,24b-dihomo-20-epivitaminD3/(22R)-1alpha,22,2"
	"2,3-Dihydroxy-3-methylvalericacid"
	"2,3-Dioxogulonicacid"
	"2,5-Dimethoxycinnamicacid"
	"2'-Deoxyuridine5'-diphosphate(dUDP)"
	"2H-1-Benzopyran-6-aceticacid,7-hydroxy-8-methoxy-2-oxo-"
	"2-Heptenedioicacid,4-oxo-"
	"2-Naphthaleneaceticacid,6-hydroxy-"
	"2-Naphthaleneaceticacid,6-hydroxy--3.1083467"
	"2-Naphthaleneaceticacid,6-hydroxy--3.220013"
	"3D,7D,11D-Phytanicacid"
	"3E,5E-tridecadienoicacid"
	"3-Hydroxy-2-methyl-[R-(R,S)]-butanoicacid"
	"4,8-dimethyl-dodecanoicacid"
	"5-[2-(hydroxymethyl)-5-methylphenoxy]-2,2-dimethyl-Pentanoicacid(GemfibrozilM4)"
	"5-(4-hydroxy-2,5-dimethylphenoxy)-2,2-dimethyl-Pentanoicacid(GemfibrozilM1)"
	"6b,11b,16a,17a,21-Pentahydroxypregna-1,4-diene-3,20-dione16,17-acetonide"
	"6b,11b,16a,17a,21-Pentahydroxypregna-1,4-diene-3,20-dione16,17-acetonide-1.9632031"
	"Benzaldehyde,p-amino-,thiosemicarbazone"
	"Propanoicacid,2-hydroxy-3-[(4-hydroxy-1-naphthalenyl)oxy]-"
Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 8 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 9 in the METABOLITES table has all null values.