Validation Log 2025-12-14 21:06:37.336701 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000146/mwtab/json Study ID: ST000092 Analysis ID: AN000146 File format: json Status: Contains Validation Issues Number of Issues: 24 Number of Warnings: 9 Number of Value Errors: 16 Number of Consistency Errors: 2 Number of Format Errors: 4 Issue Log: Error: An empty value or a null value was detected in ["PROJECT"]["PROJECT_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["PROJECT"]["ADDRESS"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["PROJECT"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["STUDY"]["ADDRESS"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["STUDY"]["PHONE"]. A legitimate value should be provided for this required key. Error: The value, "Male and Female", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The value, "0.450.5 mL/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "1 L, splitless", in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "10 L", in ["CHROMATOGRAPHY"]["SAMPLE_SYRINGE_SIZE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "1_3-dihydroxyacetone" "2_3-dihydroxybutanoic acid" "2_3-dihydroxybutyric acid 1" "2_3-dihydroxybutyric acid 2" "2_3-dihydroxybutyric acid 2" "2_4-dihydroxybutyric acid" "2-butyne-1_4-diol" "2-methyl-3-hydroxypropanoic acid_1" "3_4-dihydroxybutanoic acid" "3_4-dihydroxybutyric acid" "3_4-dihydroxybutyric acid_1" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "1,3-dihydroxyacetone" "2,3-dihydroxybutanoic acid" "2,3-dihydroxybutyric acid 1" "2,3-dihydroxybutyric acid 2" "2,3-dihydroxybutyric acid 2" "2,4-dihydroxybutyric acid" "2-butyne-1,4-diol" "3,4-dihydroxybutanoic acid" "3,4-dihydroxybutyric acid" Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "other_id" and "other_id_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.