Validation Log 2025-12-14 21:06:45.131314 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000149/mwtab/txt Study ID: ST000093 Analysis ID: AN000149 File format: txt Status: Contains Validation Issues Number of Issues: 17 Number of Warnings: 7 Number of Value Errors: 11 Number of Consistency Errors: 2 Number of Format Errors: 2 Issue Log: Error: An empty value or a null value was detected for the subsection, "ADDRESS", in the "PROJECT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "ADDRESS", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: The value, "postmenopausal women", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection. Error: The value, "60°C to 340°C", for the subsection, "CAPILLARY_TEMPERATURE", in the "MS" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "Units", in the "MS_METABOLITE_DATA" section. A legitimate value should be provided for this required subsection. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "2_3-diphosphoglycerate" "4-androsten-3beta_17beta-diol disulfate 1*" "5alpha-pregnan-3beta_20alpha-diol disulfate" "adenosine 2^-monophosphate (2^-AMP)" "adenosine 3^_5^-cyclic monophosphate (cAMP)" "adenosine 5^diphosphoribose" "Isobar: fructose 1_6-diphosphate_ glucose 1_6-diphosphate_ myo-inositol 1_4 or 1_3-diphosphate" "uridine monophosphate (5^ or 3^)" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "2,3-diphosphoglycerate" "4-androsten-3beta,17beta-diol disulfate 1*" "5alpha-pregnan-3beta,20alpha-diol disulfate" "adenosine 2'-monophosphate (2'-AMP)" "adenosine 3',5'-cyclic monophosphate (cAMP)" "adenosine 5'diphosphoribose" "Isobar: fructose 1,6-diphosphate, glucose 1,6-diphosphate, myo-inositol 1,4 or 1,3-diphosphate" "uridine monophosphate (5' or 3')" Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 4 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.