Validation Log 2025-12-14 21:06:52.759736 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000152/mwtab/json Study ID: ST000096 Analysis ID: AN000152 File format: json Status: Contains Validation Issues Number of Issues: 52 Number of Warnings: 39 Number of Value Errors: 46 Number of Consistency Errors: 2 Number of Format Errors: 3 Issue Log: Error: The value, "See protocol/methods file", in ["MS"]["ION_SOURCE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "See protocol/methods file", in ["MS"]["ION_SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "0.25", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "5 L", in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "600 L", in ["CHROMATOGRAPHY"]["WEAK_WASH_VOLUME"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "600 L", in ["CHROMATOGRAPHY"]["STRONG_WASH_VOLUME"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "17 L", in ["CHROMATOGRAPHY"]["SAMPLE_LOOP_SIZE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The required property, "CHROMATOGRAPHY_TYPE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "INSTRUMENT_NAME", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_NAME", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "11_12_15-THET" "11_12-DiHETrE" "12_13-DiHODE" "12_13-DiHOME" "14_15-DiHETE" "14_15-DiHETrE" "15_16-DiHODE" "17_18-DiHETE" "19_20-DiHDoPA" "5_15-DiHETE" "5_6-DiHETrE" "8_15-DiHETE" "8_9-DiHETrE" "9_10-13-TriHOME" "9_10-DiHODE" "9_10-DiHOME" "9_12_13-TriHOME" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "11,12,15-THET" "11,12-DiHETrE" "12,13-DiHODE" "12,13-DiHOME" "14,15-DiHETE" "14,15-DiHETrE" "15,16-DiHODE" "17,18-DiHETE" "19,20-DiHDoPA" "5,15-DiHETE" "5,6-DiHETrE" "8,15-DiHETE" "8,9-DiHETrE" "9,10-13-TriHOME" "9,10-DiHODE" "9,10-DiHOME" "9,12,13-TriHOME" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "S19C" column at position 24 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S30B" column at position 31 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S31B" column at position 32 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S32B" column at position 33 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S33B" column at position 34 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S34B" column at position 35 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S35B" column at position 36 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S17B" column at position 37 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S19B" column at position 38 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S20B" column at position 39 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S23B" column at position 40 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S24B" column at position 41 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S25B" column at position 42 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S26B" column at position 43 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "Media blank" column at position 44 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "Blank media" column at position 45 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "S29C" column at position 16 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S30C" column at position 17 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S31C" column at position 18 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S32C" column at position 19 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S33C" column at position 20 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S34C" column at position 21 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S35C" column at position 22 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S17C" column at position 23 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S20C" column at position 25 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S23C" column at position 26 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S24C" column at position 27 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S25C" column at position 28 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S26C" column at position 29 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S29B" column at position 30 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.