Validation Log 2025-12-14 21:06:51.108699 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000152/mwtab/txt Study ID: ST000096 Analysis ID: AN000152 File format: txt Status: Contains Validation Issues Number of Issues: 109 Number of Warnings: 97 Number of Value Errors: 103 Number of Consistency Errors: 2 Number of Format Errors: 3 Issue Log: Error: The value, "See protocol/methods file", for the subsection, "ION_SOURCE_TEMPERATURE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "See protocol/methods file", for the subsection, "ION_SPRAY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "0.25", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "5 L", for the subsection, "SAMPLE_INJECTION", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "600 L", for the subsection, "WEAK_WASH_VOLUME", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "600 L", for the subsection, "STRONG_WASH_VOLUME", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "17 L", for the subsection, "SAMPLE_LOOP_SIZE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The required property, "CHROMATOGRAPHY_TYPE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "INSTRUMENT_NAME", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_NAME", in the "CHROMATOGRAPHY" section is missing. Warning: There are duplicate samples in the MS_METABOLITE_DATA section. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "11_12_15-THET" "11_12-DiHETrE" "12_13-DiHODE" "12_13-DiHOME" "14_15-DiHETE" "14_15-DiHETrE" "15_16-DiHODE" "17_18-DiHETE" "19_20-DiHDoPA" "5_15-DiHETE" "5_6-DiHETrE" "8_15-DiHETE" "8_9-DiHETrE" "9_10-13-TriHOME" "9_10-DiHODE" "9_10-DiHOME" "9_12_13-TriHOME" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "11,12,15-THET" "11,12-DiHETrE" "12,13-DiHODE" "12,13-DiHOME" "14,15-DiHETE" "14,15-DiHETrE" "15,16-DiHODE" "17,18-DiHETE" "19,20-DiHDoPA" "5,15-DiHETE" "5,6-DiHETrE" "8,15-DiHETE" "8,9-DiHETrE" "9,10-13-TriHOME" "9,10-DiHODE" "9,10-DiHOME" "9,12,13-TriHOME" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The 2nd "S34C" column at position 60 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S19C" column at position 70 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S30B" column at position 90 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S30B" column at position 91 in the MS_METABOLITE_DATA table has all null values. Warning: The "S31B" column at position 92 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S31B" column at position 93 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S31B" column at position 94 in the MS_METABOLITE_DATA table has all null values. Warning: The "S32B" column at position 95 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S32B" column at position 96 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S32B" column at position 97 in the MS_METABOLITE_DATA table has all null values. Warning: The "S33B" column at position 98 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S33B" column at position 99 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S33B" column at position 100 in the MS_METABOLITE_DATA table has all null values. Warning: The "S34B" column at position 101 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S34B" column at position 102 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S34B" column at position 103 in the MS_METABOLITE_DATA table has all null values. Warning: The "S35B" column at position 104 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S35B" column at position 105 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S35B" column at position 106 in the MS_METABOLITE_DATA table has all null values. Warning: The "S17B" column at position 107 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S17B" column at position 108 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S17B" column at position 109 in the MS_METABOLITE_DATA table has all null values. Warning: The "S19B" column at position 110 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S19B" column at position 111 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S19B" column at position 112 in the MS_METABOLITE_DATA table has all null values. Warning: The "S20B" column at position 113 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S20B" column at position 114 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S20B" column at position 115 in the MS_METABOLITE_DATA table has all null values. Warning: The "S23B" column at position 116 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S23B" column at position 117 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S23B" column at position 118 in the MS_METABOLITE_DATA table has all null values. Warning: The "S24B" column at position 119 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S24B" column at position 120 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S24B" column at position 121 in the MS_METABOLITE_DATA table has all null values. Warning: The "S25B" column at position 122 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S25B" column at position 123 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S25B" column at position 124 in the MS_METABOLITE_DATA table has all null values. Warning: The "S26B" column at position 125 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S26B" column at position 126 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S26B" column at position 127 in the MS_METABOLITE_DATA table has all null values. Warning: The "Media blank" column at position 128 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "Media blank" column at position 129 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "Media blank" column at position 130 in the MS_METABOLITE_DATA table has all null values. Warning: The "Blank media" column at position 131 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "Blank media" column at position 132 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "Blank media" column at position 133 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S29C" column at position 46 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S30C" column at position 47 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S30C" column at position 48 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S30C" column at position 49 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S31C" column at position 50 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S31C" column at position 51 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S31C" column at position 52 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S32C" column at position 53 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S32C" column at position 54 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S32C" column at position 55 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S33C" column at position 56 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S33C" column at position 57 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S33C" column at position 58 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S34C" column at position 59 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S34C" column at position 61 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S35C" column at position 62 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S35C" column at position 63 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S35C" column at position 64 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S17C" column at position 65 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S17C" column at position 66 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S17C" column at position 67 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S19C" column at position 68 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S19C" column at position 69 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S20C" column at position 71 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S20C" column at position 72 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S20C" column at position 73 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S23C" column at position 74 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S23C" column at position 75 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S23C" column at position 76 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S24C" column at position 77 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S24C" column at position 78 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S24C" column at position 79 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S25C" column at position 80 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S25C" column at position 81 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S25C" column at position 82 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S26C" column at position 83 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S26C" column at position 84 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S26C" column at position 85 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S29B" column at position 86 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 2nd "S29B" column at position 87 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The 3rd "S29B" column at position 88 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S30B" column at position 89 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.