Validation Log 2026-02-08 01:20:54.201110 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000173/mwtab/txt Study ID: ST000105 Analysis ID: AN000173 File format: txt Status: Contains Validation Issues Number of Issues: 18 Number of Warnings: 7 Number of Value Errors: 11 Number of Consistency Errors: 1 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE" "1_2-DIDECANOYL-SN-GLYCERO-3-PHOSPHOCHOLINE" "1_2-DIPALMITOYL-SN-GLYCEROL" "2`_4`-DIHYDROXYACETOPHENONE" "2_6-DIHYDROXYPYRIDINE" "3_4-DIHYDROXYBENZOATE" "3_4-DIHYDROXY-L-PHENYLALANINE" "3_4-DIHYDROXYPHENYLACETATE" "3_4-DIHYDROXYPHENYL GLYCOL" "3-ALPHA_11-BETA_17-ALPHA_21-TETRAHYDROXY- 5-ALPHA-PREGNAN-20-ONE" "6_7-DIHYDROBIOPTERIN" "ADENOSINE 3`_5`-CYCLIC MONOPHOSPHATE" "CIS-7_10_13_16-DOCOSATETRAENOIC ACID" "CYCLOHEXANE-1_3-DIONE" "D-GLUCONO-1_5-LACTONE" "ENKEPHALINE_ (D-ALA)2-LEU" "GULONO-1_4-LACTONE" "LL-2_6-DIAMINOHEPTANEDIOATE" "N_N_N-TRIMETHYLLYSINE" "PYRIDINE-2_3-DICARBOXYLATE" "TRANS-CYCLOHEXANE-1_2-DIOL" "11-BETA-HYDROXYANDROST-4-ENE-3,17-DIONE_2" "11-BETA-HYDROXYANDROST-4-ENE-3,17-DIONE_3" "2,6-DIHYDROXYPYRIDINE_2" "3,4-DIHYDROXYBENZOATE_2" "CYCLOHEXANE-1,3-DIONE_2" Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the METABOLITES table has all null values. Warning: The "ri" column at position 3 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 4 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.