Validation Log 2025-12-14 21:07:55.939493 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000175/mwtab/txt Study ID: ST000106 Analysis ID: AN000175 File format: txt Status: Contains Validation Issues Number of Issues: 19 Number of Warnings: 7 Number of Value Errors: 11 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected for the subsection, "ADDRESS", in the "PROJECT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "10-HYDROXYDECANOATE_1" "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE" "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE_1" "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE_2" "1_2-DIDECANOYL-SN-GLYCERO-3-PHOSPHOCHOLINE" "12-HYDROXY-DODECANOIC ACID_1" "2`_4`-DIHYDROXYACETOPHENONE" "2_6-DIHYDROXYPYRIDINE" "2`-DEOXYADENOSINE_1" "2`-DEOXYCYTIDINE_1" "2`-DEOXYGUANOSINE_1" "2-HYDROXY-4-(METHYLTHIO)BUTYRIC ACID_1" "2-HYDROXYBUTYRIC ACID_1" "2-QUINOLINECARBOXYLIC ACID_1" "3_3`_5-TRIIODO-L-THYRONINE" "3_3`-DITHIODIVALINE" "3_3`-DITHIODIVALINE_1" "3_4-DICHLOROANILINE" "3_4-DIHYDROXYBENZOATE" "3_4-DIHYDROXYBENZOATE_1" "3_4-DIHYDROXY-L-PHENYLALANINE" "3_4-DIHYDROXYPHENYLACETATE" "3_5-DIIODO-L-THYRONINE" "3-ALPHA_11-BETA_17-ALPHA_21-TETRAHYDROXY- 5-ALPHA-PREGNAN-20-ONE" "3-(CYSTEIN-S-YL)ACETAMINOPHEN (*)_1" "3-HYDROXY-3-METHYLGLUTARATE_1" "3-METHOXY-L-TYROSINE_1" "3-METHYL-2-OXINDOLE_1" "4-ACETAMIDOBUTANOATE_1" "4-AMINOBENZOYLGLUTAMIC ACID_1" "4-METHYL-2-OXOPENTANOATE_1" "5`-DEOXYADENOSINE_1" "5-HYDROXYINDOLE-3-ACETIC ACID_1" "5`-METHYLTHIOADENOSINE_1" "6_7-DIHYDROBIOPTERIN" "ADENOSINE 3`_5`-CYCLIC MONOPHOSPHATE" "ALPHA-KETO-GLUTARATE_1" "ALPHA-TOCOPHEROL_1" "ASPARAGINE_1" "AZELAIC ACID_1" "BILIVERDIN_1" "BIOTIN_1" "BIS(2-ETHYLHEXYL)PHTHALATE_1" "BISPHOSPHOGLYCERATE_1" "BOC-ALA-OH_1" "BOC-HIS-OH_1" "BOC-LYS-OH_1" "BRADYKININ DES-ARG(9) (*)_1" "BUTYRYLCARNITINE (*)_1" "CAFFEINE_1" "CAPECITABINE_1" "C-GLYCOSYLTRYPTOPHAN (*)_1" "CIS-4-DECENOYL CARNITINE (*)_1" "CIS-7_10_13_16-DOCOSATETRAENOIC ACID" "CITRATE_1" "CORTICOSTERONE_1" "CORTISOL_1" "CORTISOL 21-ACETATE_1" "CORTISONE_1" "COTININE (*)_1" "CYCLOHEXANE-1_3-DIONE" "CYCLOHEXANE-1_3-DIONE_1" "CYSTINE_1" "DEOXYCHOLATE_1" "DEOXYCORTICOSTERONE_1" "DETHIOBIOTIN_1" "D-GLUCONO-1_5-LACTONE" "DIETHYL AMINOMALONATE_1" "DIHYDROFOLATE_1" "DIHYDROOROTATE_1" "DIMETHYLBENZIMIDAZOLE_1" "DIMETHYL MALEATE_1" "DOCOSAHEXAENOIC ACID_1" "DOCOSAHEXAENOYLGLYCEROPHOSPHOCHOLINE (*)_1" "EDTA (*)_1" "ENKEPHALINE_ (D-ALA)2-LEU" "ETHYL 4-OXOCYCLOHEXANECARBOXYLATE_1" "FERULATE_1" "FOLIC ACID_1" "FORMYL-L-METHIONINE_1" "GLUTAMINE_1" "GLUTARATE_1" "GLYCERALDEHYDE 3-PHOSPHATE DIETHYL ACETAL_1" "GLYCOCHOLATE_1" "GLYCOLITHOCHOLIC ACID ETHYL ESTER_1" "GUANOSINE 5`-DIPHOSPHATE_1" "GULONO-1_4-LACTONE" "HIPPURATE_1" "HOMOGENTISATE_1" "HOMOVANILLATE_1" "HYDROXYBENZOIC ACID_1" "HYPOXANTHINE_1" "INDOLE-3-ACETALDEHYDE_1" "INDOLE-3-ACETAMIDE_1" "INDOLE-3-ACETIC ACID_1" "INOSINE_1" "INOSINE 5`-MONOPHOSPHATE_1" "KYNURENIC ACID_1" "LINOLEOYLGLYCEROPHOSPHOCHOLINE (*)_1" "LL-2_6-DIAMINOHEPTANEDIOATE" "LUMICHROME_1" "MANNOSE-6-PHOSPHATE_1" "MELATONIN_1" "METHYL ACETOACETATE_1" "METHYL JASMONATE_1" "MYRISTOYLGLYCEROPHOSPHOCHOLINE (*)_1" "N1-METHYL-2-PYRIDONE-5-CARBOXAMIDE (*)_1" "N6-(DELTA2-ISOPENTENYL)-ADENINE_1" "N-ACETYL-D-HEXOSAMINE_1" "N-ACETYL-DL-METHIONINE_1" "N-ACETYL-D-TRYPTOPHAN_1" "N-ACETYL-L-ASPARTIC ACID_1" "N-ACETYL-L-CYSTEINE_1" "N-ACETYL-L-PHENYLALANINE_1" "N-ACETYLSEROTONIN_1" "N-BENZYLOXYCARBONYLGLYCINE_1" "N-CYCLOHEXYLFORMAMIDE_1" "N-CYCLOHEXYLSULFAMIC ACID_1" "N_N_N-TRIMETHYLLYSINE" "O-ACETYL-L-CARNITINE_1" "OLEAMIDE_1" "OLEOYLCARNITINE (*)_1" "OLEOYLGLYCEROPHOSPHOCHOLINE (*)_1" "O-PHOSPHO-DL-SERINE_1" "ORNITHINE_1" "PANTOLACTONE_1" "PANTOTHENIC ACID_1" "PHENYLACETIC ACID_1" "PHENYLALANINE_1" "PHOSPHONOACETATE_1" "PROGESTERONE_1" "PROMETRYN_1" "PTERIN_1" "PYRIDINE-2_3-DICARBOXYLATE" "QUINOLIN-2-OL_1" "RETINAL_1" "RETINOATE_1" "S-ADENOSYL-L-HOMOCYSTEINE_1" "SALSOLINOL_1" "S-HEXYL-GLUTATHIONE_1" "SPHINGANINE_1" "STEAROYL SPHINGOMYELIN (*)_1" "SUBERIC ACID_1" "TAURINE_1" "TESTOSTERONE_1" "THYMIDINE_1" "THYROXINE_1" "TRANS-CYCLOHEXANE-1_2-DIOL" "TRIGONELLINE_1" "TRYPTOPHAN_1" "TRYPTOPHANAMIDE_1" "TRYPTOPHAN BETAINE (*)_1" "UREA_1" "URIDINE_1" "VALINE_1" "VALINE (*)_1" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "10-HYDROXYDECANOATE_3" "12-HYDROXY-DODECANOIC ACID_2" "2`-DEOXYADENOSINE_2" "2`-DEOXYCYTIDINE_2" "2`-DEOXYGUANOSINE_3" "2-HYDROXY-4-(METHYLTHIO)BUTYRIC ACID_2" "2-HYDROXYBUTYRIC ACID_2" "2-QUINOLINECARBOXYLIC ACID_2" "3-(CYSTEIN-S-YL)ACETAMINOPHEN (*)_2" "3-HYDROXY-3-METHYLGLUTARATE_2" "3-METHOXY-L-TYROSINE_2" "3-METHYL-2-OXINDOLE_2" "4-ACETAMIDOBUTANOATE_2" "4-AMINOBENZOYLGLUTAMIC ACID_3" "4-METHYL-2-OXOPENTANOATE_2" "5`-DEOXYADENOSINE_3" "5-HYDROXYINDOLE-3-ACETIC ACID_2" "5`-METHYLTHIOADENOSINE_2" "ALPHA-KETO-GLUTARATE_2" "ALPHA-TOCOPHEROL_2" "ASPARAGINE_2" "AZELAIC ACID_2" "BILIVERDIN_4" "BIOTIN_4" "BIS(2-ETHYLHEXYL)PHTHALATE_3" "BISPHOSPHOGLYCERATE_2" "BOC-ALA-OH_2" "BOC-HIS-OH_4" "BOC-LYS-OH_3" "BRADYKININ DES-ARG(9) (*)_2" "BUTYRYLCARNITINE (*)_2" "CAFFEINE_2" "CAPECITABINE_4" "C-GLYCOSYLTRYPTOPHAN (*)_2" "CIS-4-DECENOYL CARNITINE (*)_2" "CITRATE_2" "CORTICOSTERONE_3" "CORTISOL_3" "CORTISOL 21-ACETATE_3" "CORTISONE_3" "COTININE (*)_2" "CYSTINE_2" "DEOXYCHOLATE_2" "DEOXYCORTICOSTERONE_3" "DETHIOBIOTIN_2" "DIETHYL AMINOMALONATE_2" "DIHYDROFOLATE_2" "DIHYDROOROTATE_4" "DIMETHYLBENZIMIDAZOLE_2" "DIMETHYL MALEATE_2" "DOCOSAHEXAENOIC ACID_3" "DOCOSAHEXAENOYLGLYCEROPHOSPHOCHOLINE (*)_2" "EDTA (*)_2" "ETHYL 4-OXOCYCLOHEXANECARBOXYLATE_2" "FERULATE_2" "FOLIC ACID_2" "FORMYL-L-METHIONINE_2" "GLUTAMINE_2" "GLUTARATE_2" "GLYCERALDEHYDE 3-PHOSPHATE DIETHYL ACETAL_2" "GLYCOCHOLATE_2" "GLYCOLITHOCHOLIC ACID ETHYL ESTER_3" "GUANOSINE 5`-DIPHOSPHATE_2" "HIPPURATE_2" "HOMOGENTISATE_2" "HOMOVANILLATE_2" "HYDROXYBENZOIC ACID_2" "HYPOXANTHINE_2" "INDOLE-3-ACETALDEHYDE_2" "INDOLE-3-ACETAMIDE_3" "INDOLE-3-ACETIC ACID_2" "INOSINE_2" "INOSINE 5`-MONOPHOSPHATE_2" "KYNURENIC ACID_2" "LINOLEOYLGLYCEROPHOSPHOCHOLINE (*)_2" "LUMICHROME_3" "MANNOSE-6-PHOSPHATE_2" "MELATONIN_4" "METHYL ACETOACETATE_2" "METHYL JASMONATE_2" "MYRISTOYLGLYCEROPHOSPHOCHOLINE (*)_2" "N1-METHYL-2-PYRIDONE-5-CARBOXAMIDE (*)_3" "N6-(DELTA2-ISOPENTENYL)-ADENINE_3" "N-ACETYL-D-HEXOSAMINE_2" "N-ACETYL-DL-METHIONINE_3" "N-ACETYL-D-TRYPTOPHAN_2" "N-ACETYL-L-ASPARTIC ACID_2" "N-ACETYL-L-CYSTEINE_2" "N-ACETYL-L-PHENYLALANINE_3" "N-ACETYLSEROTONIN_4" "N-BENZYLOXYCARBONYLGLYCINE_2" "N-CYCLOHEXYLFORMAMIDE_4" "N-CYCLOHEXYLSULFAMIC ACID_2" "O-ACETYL-L-CARNITINE_2" "OLEAMIDE_2" "OLEOYLCARNITINE (*)_2" "OLEOYLGLYCEROPHOSPHOCHOLINE (*)_3" "O-PHOSPHO-DL-SERINE_2" "ORNITHINE_2" "PANTOLACTONE_2" "PANTOTHENIC ACID_2" "PHENYLACETIC ACID_2" "PHENYLALANINE_2" "PHOSPHONOACETATE_2" "PROGESTERONE_2" "PROMETRYN_2" "PTERIN_2" "QUINOLIN-2-OL_2" "RETINAL_2" "RETINOATE_2" "S-ADENOSYL-L-HOMOCYSTEINE_2" "SALSOLINOL_2" "S-HEXYL-GLUTATHIONE_2" "SPHINGANINE_2" "STEAROYL SPHINGOMYELIN (*)_2" "SUBERIC ACID_2" "TAURINE_3" "TESTOSTERONE_2" "THYMIDINE_2" "THYROXINE_2" "TRIGONELLINE_2" "TRYPTOPHAN_2" "TRYPTOPHANAMIDE_2" "TRYPTOPHAN BETAINE (*)_4" "UREA_2" "URIDINE_3" "VALINE_2" "VALINE (*)_2" Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the METABOLITES table has all null values. Warning: The "ri" column at position 3 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 4 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.