Validation Log 2025-12-14 21:08:01.856757 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000176/mwtab/json Study ID: ST000106 Analysis ID: AN000176 File format: json Status: Contains Validation Issues Number of Issues: 62 Number of Warnings: 50 Number of Value Errors: 54 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected in ["PROJECT"]["ADDRESS"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["STUDY"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["COLLECTION"]["COLLECTION_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLEPREP_SUMMARY"]. A legitimate value should be provided for this required key. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "11-BETA-HYDROXYANDROST-4-ENE-3_17-DIONE" "1_2-DIDECANOYL-SN-GLYCERO-3-PHOSPHOCHOLINE" "2_3_5_6-TETRACHLOROPHENOL" "2_3-DIPHOSPHO-D-GLYCERIC ACID" "2`_4`-DIHYDROXYACETOPHENONE" "2_5-DIOXOPIPERAZINE" "3_4-DIHYDROXYBENZOATE" "3_4-DIHYDROXYPHENYL GLYCOL" "3_5-DIBROMO-4-HYDROXYBENZONITRILE" "3-CARBOXY-4-METHYL-5-PROPYL-2-FURANPROPANOATE_1" "4-ANDROSTEN-3BETA_17BETA-DIOL DISULFATE (*)" "5_6-DIHYDROURACIL" "ADENOSINE 3`_5`-CYCLIC MONOPHOSPHATE" "CIS-7_10_13_16-DOCOSATETRAENOIC ACID" "CYTIDINE 2`_3`-CYCLIC MONOPHOSPHATE" "DEHYDROISOANDROSTERONE 3-SULFATE_1" "GULONO-1_4-LACTONE" "LL-2_6-DIAMINOHEPTANEDIOATE" "NICOTINAMIDE ADENINE DINUCLEOTIDE_1" "PYRIDINE-2_3-DICARBOXYLATE" "PYRIDOXAL_1" "RIBULOSE 1_5-BISPHOSPHATE" "STEAROYLGLYCEROPHOSPHOETHANOLAMINE (*)_1" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "3-CARBOXY-4-METHYL-5-PROPYL-2-FURANPROPANOATE_2" "DEHYDROISOANDROSTERONE 3-SULFATE_2" "NICOTINAMIDE ADENINE DINUCLEOTIDE_2" "PYRIDOXAL_2" "STEAROYLGLYCEROPHOSPHOETHANOLAMINE (*)_2" Warning: The "kegg_id" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 115 BOCALA 117 BOCASN Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "S00009775" column at position 22 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009779" column at position 23 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009728" column at position 24 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009732" column at position 25 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009736" column at position 26 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009740" column at position 27 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009744" column at position 28 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009748" column at position 29 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009752" column at position 30 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009756" column at position 31 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009760" column at position 32 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009764" column at position 33 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009768" column at position 34 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009772" column at position 35 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009776" column at position 36 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009780" column at position 37 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009729" column at position 38 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009733" column at position 39 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009737" column at position 40 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009741" column at position 41 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009745" column at position 42 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009749" column at position 43 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009753" column at position 44 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009757" column at position 45 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009761" column at position 46 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009765" column at position 47 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009769" column at position 48 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009773" column at position 49 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009777" column at position 50 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009781" column at position 51 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009730" column at position 52 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009734" column at position 53 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009738" column at position 54 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009742" column at position 55 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009746" column at position 56 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009750" column at position 57 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009758" column at position 58 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009762" column at position 59 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009766" column at position 60 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009770" column at position 61 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009774" column at position 62 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "S00009782" column at position 63 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "moverz_quant" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.