Validation Log 2025-12-14 21:08:32.576219 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000191/mwtab/json Study ID: ST000113 Analysis ID: AN000191 File format: json Status: Contains Validation Issues Number of Issues: 27 Number of Warnings: 11 Number of Value Errors: 18 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected in ["PROJECT"]["ADDRESS"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["PROJECT"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["STUDY"]["ADDRESS"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["STUDY"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["COLLECTION"]["COLLECTION_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLEPREP_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["INSTRUMENT_NAME"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["COLUMN_NAME"]. A legitimate value should be provided for this required key. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "a-glycerol-3P_1-[13C_15N]0" "a-glycerol-3P_1-[13C_15N]1" "a-glycerol-3P_1-[13C_15N]2" "a-glycerol-3P_1-[13C_15N]3" "a-glycerol-3P_2-[13C_15N]0" "a-glycerol-3P_2-[13C_15N]1" "a-glycerol-3P_2-[13C_15N]2" "a-glycerol-3P_2-[13C_15N]3" "a-ketoglutarate-[13C_15N]0" "a-ketoglutarate-[13C_15N]1" "a-ketoglutarate-[13C_15N]2" "a-ketoglutarate-[13C_15N]3" "a-ketoglutarate-[13C_15N]4" "a-ketoglutarate-[13C_15N]5" "Ala-[13C_15N]0" "Ala-[13C_15N]1" "Ala-[13C_15N]2" "Ala-[13C_15N]3" "Arg-[13C_15N]0" "Arg-[13C_15N]1" "Arg-[13C_15N]2" "Arg-[13C_15N]3" "Arg-[13C_15N]4" "Arg-[13C_15N]5" "Arg-[13C_15N]6" "ascorbate-[13C_15N]0" "ascorbate-[13C_15N]1" "ascorbate-[13C_15N]2" "ascorbate-[13C_15N]3" "ascorbate-[13C_15N]4" "ascorbate-[13C_15N]5" "ascorbate-[13C_15N]6" "Asn-[13C_15N]0" "Asn-[13C_15N]1" "Asn-[13C_15N]2" "Asn-[13C_15N]3" "Asn-[13C_15N]4" "Asp-[13C_15N]0" "Asp-[13C_15N]1" "Asp-[13C_15N]2" "Asp-[13C_15N]3" "Asp-[13C_15N]4" "bOHbutyrate-[13C_15N]0" "bOHbutyrate-[13C_15N]1" "bOHbutyrate-[13C_15N]2" "bOHbutyrate-[13C_15N]3" "bOHbutyrate-[13C_15N]4" "citrate-[13C_15N]0" "citrate-[13C_15N]1" "citrate-[13C_15N]2" "citrate-[13C_15N]3" "citrate-[13C_15N]4" "citrate-[13C_15N]5" "citrate-[13C_15N]6" "Cys-[13C_15N]0" "Cys-[13C_15N]1" "Cys-[13C_15N]2" "Cys-[13C_15N]3" "fumarate-[13C_15N]0" "fumarate-[13C_15N]1" "fumarate-[13C_15N]2" "fumarate-[13C_15N]3" "fumarate-[13C_15N]4" "GAB-[13C_15N]0" "GAB-[13C_15N]1" "GAB-[13C_15N]2" "GAB-[13C_15N]3" "GAB-[13C_15N]4" "Gln-[13C_15N]0" "Gln-[13C_15N]1" "Gln-[13C_15N]2" "Gln-[13C_15N]3" "Gln-[13C_15N]4" "Gln-[13C_15N]5" "Glu-[13C_15N]0" "Glu-[13C_15N]1" "Glu-[13C_15N]2" "Glu-[13C_15N]3" "Glu-[13C_15N]4" "Glu-[13C_15N]5" "Gly-[13C_15N]0" "Gly-[13C_15N]1" "Gly-[13C_15N]2" "His-[13C_15N]0" "His-[13C_15N]1" "His-[13C_15N]2" "His-[13C_15N]3" "His-[13C_15N]4" "His-[13C_15N]5" "His-[13C_15N]6" "Ile-[13C_15N]0" "Ile-[13C_15N]1" "Ile-[13C_15N]2" "Ile-[13C_15N]3" "Ile-[13C_15N]4" "Ile-[13C_15N]5" "Ile-[13C_15N]6" "lactate-[13C_15N]0" "lactate-[13C_15N]1" "lactate-[13C_15N]2" "lactate-[13C_15N]3" "Leu-[13C_15N]0" "Leu-[13C_15N]1" "Leu-[13C_15N]2" "Leu-[13C_15N]3" "Leu-[13C_15N]4" "Leu-[13C_15N]5" "Leu-[13C_15N]6" "Lys-[13C_15N]0" "Lys-[13C_15N]1" "Lys-[13C_15N]2" "Lys-[13C_15N]3" "Lys-[13C_15N]4" "Lys-[13C_15N]5" "Lys-[13C_15N]6" "Malate-[13C_15N]0" "Malate-[13C_15N]1" "Malate-[13C_15N]2" "Malate-[13C_15N]3" "Malate-[13C_15N]4" "Met-[13C_15N]0" "Met-[13C_15N]1" "Met-[13C_15N]2" "Met-[13C_15N]3" "Met-[13C_15N]4" "Met-[13C_15N]5" "OHPro-[13C_15N]0" "OHPro-[13C_15N]1" "OHPro-[13C_15N]2" "OHPro-[13C_15N]3" "OHPro-[13C_15N]4" "OHPro-[13C_15N]5" "Orn-[13C_15N]0" "Orn-[13C_15N]1" "Orn-[13C_15N]2" "Orn-[13C_15N]3" "Orn-[13C_15N]4" "Orn-[13C_15N]5" "Phe-[13C_15N]0" "Phe-[13C_15N]1" "Phe-[13C_15N]2" "Phe-[13C_15N]3" "Phe-[13C_15N]4" "Phe-[13C_15N]5" "Phe-[13C_15N]6" "Phe-[13C_15N]7" "Phe-[13C_15N]8" "Phe-[13C_15N]9" "Pro258-[13C_15N]0" "Pro258-[13C_15N]1" "Pro258-[13C_15N]2" "Pro258-[13C_15N]3" "Pro258-[13C_15N]4" "Pro258-[13C_15N]5" "Ser-[13C_15N]0" "Ser-[13C_15N]1" "Ser-[13C_15N]2" "Ser-[13C_15N]3" "Succinate-[13C_15N]0" "Succinate-[13C_15N]1" "Succinate-[13C_15N]2" "Succinate-[13C_15N]3" "Succinate-[13C_15N]4" "t-aconitate-[13C_15N]0" "t-aconitate-[13C_15N]1" "t-aconitate-[13C_15N]2" "t-aconitate-[13C_15N]3" "t-aconitate-[13C_15N]4" "t-aconitate-[13C_15N]5" "t-aconitate-[13C_15N]6" "Thr-[13C_15N]0" "Thr-[13C_15N]1" "Thr-[13C_15N]2" "Thr-[13C_15N]3" "Thr-[13C_15N]4" "Trp-[13C_15N]0" "Trp-[13C_15N]1" "Trp-[13C_15N]10" "Trp-[13C_15N]11" "Trp-[13C_15N]2" "Trp-[13C_15N]3" "Trp-[13C_15N]4" "Trp-[13C_15N]5" "Trp-[13C_15N]6" "Trp-[13C_15N]7" "Trp-[13C_15N]8" "Trp-[13C_15N]9" "Tyr-[13C_15N]0" "Tyr-[13C_15N]1" "Tyr-[13C_15N]2" "Tyr-[13C_15N]3" "Tyr-[13C_15N]4" "Tyr-[13C_15N]5" "Tyr-[13C_15N]6" "Tyr-[13C_15N]7" "Tyr-[13C_15N]8" "Tyr-[13C_15N]9" "Val-[13C_15N]0" "Val-[13C_15N]1" "Val-[13C_15N]2" "Val-[13C_15N]3" "Val-[13C_15N]4" "Val-[13C_15N]5" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "a-glycerol-3P_1-[13C,15N]0" "a-glycerol-3P_1-[13C,15N]1" "a-glycerol-3P_1-[13C,15N]2" "a-glycerol-3P_1-[13C,15N]3" "a-glycerol-3P_2-[13C,15N]0" "a-glycerol-3P_2-[13C,15N]1" "a-glycerol-3P_2-[13C,15N]2" "a-glycerol-3P_2-[13C,15N]3" "a-ketoglutarate-[13C,15N]0" "a-ketoglutarate-[13C,15N]1" "a-ketoglutarate-[13C,15N]2" "a-ketoglutarate-[13C,15N]3" "a-ketoglutarate-[13C,15N]4" "a-ketoglutarate-[13C,15N]5" "Ala-[13C,15N]0" "Ala-[13C,15N]1" "Ala-[13C,15N]2" "Ala-[13C,15N]3" "Arg-[13C,15N]0" "Arg-[13C,15N]1" "Arg-[13C,15N]2" "Arg-[13C,15N]3" "Arg-[13C,15N]4" "Arg-[13C,15N]5" "Arg-[13C,15N]6" "ascorbate-[13C,15N]0" "ascorbate-[13C,15N]1" "ascorbate-[13C,15N]2" "ascorbate-[13C,15N]3" "ascorbate-[13C,15N]4" "ascorbate-[13C,15N]5" "ascorbate-[13C,15N]6" "Asn-[13C,15N]0" "Asn-[13C,15N]1" "Asn-[13C,15N]2" "Asn-[13C,15N]3" "Asn-[13C,15N]4" "Asp-[13C,15N]0" "Asp-[13C,15N]1" "Asp-[13C,15N]2" "Asp-[13C,15N]3" "Asp-[13C,15N]4" "bOHbutyrate-[13C,15N]0" "bOHbutyrate-[13C,15N]1" "bOHbutyrate-[13C,15N]2" "bOHbutyrate-[13C,15N]3" "bOHbutyrate-[13C,15N]4" "citrate-[13C,15N]0" "citrate-[13C,15N]1" "citrate-[13C,15N]2" "citrate-[13C,15N]3" "citrate-[13C,15N]4" "citrate-[13C,15N]5" "citrate-[13C,15N]6" "Cys-[13C,15N]0" "Cys-[13C,15N]1" "Cys-[13C,15N]2" "Cys-[13C,15N]3" "fumarate-[13C,15N]0" "fumarate-[13C,15N]1" "fumarate-[13C,15N]2" "fumarate-[13C,15N]3" "fumarate-[13C,15N]4" "GAB-[13C,15N]0" "GAB-[13C,15N]1" "GAB-[13C,15N]2" "GAB-[13C,15N]3" "GAB-[13C,15N]4" "Gln-[13C,15N]0" "Gln-[13C,15N]1" "Gln-[13C,15N]2" "Gln-[13C,15N]3" "Gln-[13C,15N]4" "Gln-[13C,15N]5" "Glu-[13C,15N]0" "Glu-[13C,15N]1" "Glu-[13C,15N]2" "Glu-[13C,15N]3" "Glu-[13C,15N]4" "Glu-[13C,15N]5" "Gly-[13C,15N]0" "Gly-[13C,15N]1" "Gly-[13C,15N]2" "His-[13C,15N]0" "His-[13C,15N]1" "His-[13C,15N]2" "His-[13C,15N]3" "His-[13C,15N]4" "His-[13C,15N]5" "His-[13C,15N]6" "Ile-[13C,15N]0" "Ile-[13C,15N]1" "Ile-[13C,15N]2" "Ile-[13C,15N]3" "Ile-[13C,15N]4" "Ile-[13C,15N]5" "Ile-[13C,15N]6" "lactate-[13C,15N]0" "lactate-[13C,15N]1" "lactate-[13C,15N]2" "lactate-[13C,15N]3" "Leu-[13C,15N]0" "Leu-[13C,15N]1" "Leu-[13C,15N]2" "Leu-[13C,15N]3" "Leu-[13C,15N]4" "Leu-[13C,15N]5" "Leu-[13C,15N]6" "Lys-[13C,15N]0" "Lys-[13C,15N]1" "Lys-[13C,15N]2" "Lys-[13C,15N]3" "Lys-[13C,15N]4" "Lys-[13C,15N]5" "Lys-[13C,15N]6" "Malate-[13C,15N]0" "Malate-[13C,15N]1" "Malate-[13C,15N]2" "Malate-[13C,15N]3" "Malate-[13C,15N]4" "Met-[13C,15N]0" "Met-[13C,15N]1" "Met-[13C,15N]2" "Met-[13C,15N]3" "Met-[13C,15N]4" "Met-[13C,15N]5" "OHPro-[13C,15N]0" "OHPro-[13C,15N]1" "OHPro-[13C,15N]2" "OHPro-[13C,15N]3" "OHPro-[13C,15N]4" "OHPro-[13C,15N]5" "Orn-[13C,15N]0" "Orn-[13C,15N]1" "Orn-[13C,15N]2" "Orn-[13C,15N]3" "Orn-[13C,15N]4" "Orn-[13C,15N]5" "Phe-[13C,15N]0" "Phe-[13C,15N]1" "Phe-[13C,15N]2" "Phe-[13C,15N]3" "Phe-[13C,15N]4" "Phe-[13C,15N]5" "Phe-[13C,15N]6" "Phe-[13C,15N]7" "Phe-[13C,15N]8" "Phe-[13C,15N]9" "Pro258-[13C,15N]0" "Pro258-[13C,15N]1" "Pro258-[13C,15N]2" "Pro258-[13C,15N]3" "Pro258-[13C,15N]4" "Pro258-[13C,15N]5" "Ser-[13C,15N]0" "Ser-[13C,15N]1" "Ser-[13C,15N]2" "Ser-[13C,15N]3" "Succinate-[13C,15N]0" "Succinate-[13C,15N]1" "Succinate-[13C,15N]2" "Succinate-[13C,15N]3" "Succinate-[13C,15N]4" "t-aconitate-[13C,15N]0" "t-aconitate-[13C,15N]1" "t-aconitate-[13C,15N]2" "t-aconitate-[13C,15N]3" "t-aconitate-[13C,15N]4" "t-aconitate-[13C,15N]5" "t-aconitate-[13C,15N]6" "Thr-[13C,15N]0" "Thr-[13C,15N]1" "Thr-[13C,15N]2" "Thr-[13C,15N]3" "Thr-[13C,15N]4" "Trp-[13C,15N]0" "Trp-[13C,15N]1" "Trp-[13C,15N]10" "Trp-[13C,15N]11" "Trp-[13C,15N]2" "Trp-[13C,15N]3" "Trp-[13C,15N]4" "Trp-[13C,15N]5" "Trp-[13C,15N]6" "Trp-[13C,15N]7" "Trp-[13C,15N]8" "Trp-[13C,15N]9" "Tyr-[13C,15N]0" "Tyr-[13C,15N]1" "Tyr-[13C,15N]2" "Tyr-[13C,15N]3" "Tyr-[13C,15N]4" "Tyr-[13C,15N]5" "Tyr-[13C,15N]6" "Tyr-[13C,15N]7" "Tyr-[13C,15N]8" "Tyr-[13C,15N]9" "Val-[13C,15N]0" "Val-[13C,15N]1" "Val-[13C,15N]2" "Val-[13C,15N]3" "Val-[13C,15N]4" "Val-[13C,15N]5" Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "other_id" and "other_id_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "moverz_quant" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "pubchem_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.