Validation Log
2025-12-14 21:09:01.984704
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000200/mwtab/txt
Study ID:      ST000119
Analysis ID:   AN000200
File format:   txt
Status: Contains Validation Issues
Number of Issues: 28

Number of Warnings: 11

Number of Value Errors: 25

Number of Consistency Errors: 1

Number of Format Errors: 0

Issue Log:
Error: An empty value or a null value was detected for the subsection, "PROJECT_SUMMARY", in the "PROJECT" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "PHONE", in the "PROJECT" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection.
Error: The value, "3000", for the subsection, "CAPILLARY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required.
Error: The value, "Nebulizer: 10 L/min  Sheath: 9 L/min", for the subsection, "DRY_GAS_FLOW", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "Nebulizer and Sheath: 350", for the subsection, "DRY_GAS_TEMP", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "125", for the subsection, "FRAGMENT_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V']. Ignore this when more complicated descriptions are required.
Error: The value, "Positive", for the subsection, "IONIZATION", in the "MS" section should not be "positive" or "negative". "ION_MODE" is where that should be indicated.
Error: The value, "750", for the subsection, "OCTPOLE_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V']. Ignore this when more complicated descriptions are required.
Error: The value, "300 bar (max)", for the subsection, "COLUMN_PRESSURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['psi', 'bar']. Ignore this when more complicated descriptions are required.
Error: The value, "4C", for the subsection, "INJECTION_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required.
Error: The value, "15 seconds", for the subsection, "WEAK_WASH_VOLUME", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required.
Error: The value, "Autosampler temperature 4C", for the subsection, "TARGET_SAMPLE_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"5'-Methylthioadenosine"
Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "other_id" and "other_id_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "pubchem_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.
Warning: The "kegg_id" column at position 7 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 8 in the METABOLITES table has all null values.
Warning: The "ri" column at position 3 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.
Warning: The "ri_type" column at position 4 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.
Warning: The "other_id_type" column at position 9 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.