Validation Log 2025-12-14 21:11:36.315910 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000271/mwtab/txt Study ID: ST000176 Analysis ID: AN000271 File format: txt Status: Contains Validation Issues Number of Issues: 244 Number of Warnings: 232 Number of Value Errors: 236 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: There are duplicate samples in the MS_METABOLITE_DATA section. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "fructose 1_6-bisphosphate" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "fructose 1,6-bisphosphate" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The 15th "S00014600" column at position 16 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014600" column at position 17 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014600" column at position 18 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014601" column at position 19 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014601" column at position 20 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014601" column at position 21 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014601" column at position 22 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014601" column at position 23 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014601" column at position 24 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014601" column at position 25 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014601" column at position 26 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014601" column at position 27 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014601" column at position 28 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014601" column at position 29 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014601" column at position 30 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014601" column at position 31 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014601" column at position 32 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014601" column at position 33 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014601" column at position 34 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014601" column at position 35 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014602" column at position 36 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014602" column at position 37 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014602" column at position 38 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014602" column at position 39 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014602" column at position 40 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014602" column at position 41 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014602" column at position 42 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014602" column at position 43 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014602" column at position 44 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014602" column at position 45 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014602" column at position 46 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014602" column at position 47 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014602" column at position 48 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014602" column at position 49 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014602" column at position 50 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014602" column at position 51 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014602" column at position 52 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014606" column at position 53 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014606" column at position 54 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014606" column at position 55 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014606" column at position 56 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014606" column at position 57 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014606" column at position 58 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014606" column at position 59 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014606" column at position 60 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014606" column at position 61 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014606" column at position 62 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014606" column at position 63 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014606" column at position 64 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014606" column at position 65 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014606" column at position 66 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014606" column at position 67 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014606" column at position 68 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014606" column at position 69 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014607" column at position 70 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014607" column at position 71 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014607" column at position 72 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014607" column at position 73 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014607" column at position 74 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014607" column at position 75 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014607" column at position 76 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014607" column at position 77 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014607" column at position 78 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014607" column at position 79 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014607" column at position 80 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014607" column at position 81 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014607" column at position 82 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014607" column at position 83 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014607" column at position 84 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014607" column at position 85 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014607" column at position 86 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014608" column at position 87 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014608" column at position 88 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014608" column at position 89 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014608" column at position 90 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014608" column at position 91 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014608" column at position 92 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014608" column at position 93 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014608" column at position 94 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014608" column at position 95 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014608" column at position 96 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014608" column at position 97 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014608" column at position 98 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014608" column at position 99 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014608" column at position 100 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014608" column at position 101 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014608" column at position 102 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014608" column at position 103 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014609" column at position 104 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014609" column at position 105 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014609" column at position 106 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014609" column at position 107 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014609" column at position 108 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014609" column at position 109 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014609" column at position 110 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014609" column at position 111 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014609" column at position 112 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014609" column at position 113 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014609" column at position 114 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014609" column at position 115 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014609" column at position 116 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014609" column at position 117 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014609" column at position 118 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014609" column at position 119 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014609" column at position 120 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014603" column at position 121 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014603" column at position 122 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014603" column at position 123 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014603" column at position 124 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014603" column at position 125 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014603" column at position 126 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014603" column at position 127 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014603" column at position 128 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014603" column at position 129 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014603" column at position 130 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014603" column at position 131 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014603" column at position 132 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014603" column at position 133 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014603" column at position 134 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014603" column at position 135 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014603" column at position 136 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014603" column at position 137 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014604" column at position 138 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014604" column at position 139 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014604" column at position 140 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014604" column at position 141 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014604" column at position 142 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014604" column at position 143 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014604" column at position 144 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014604" column at position 145 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014604" column at position 146 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014604" column at position 147 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014604" column at position 148 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014604" column at position 149 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014604" column at position 150 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014604" column at position 151 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014604" column at position 152 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014604" column at position 153 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014604" column at position 154 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014605" column at position 155 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014605" column at position 156 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014605" column at position 157 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014605" column at position 158 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014605" column at position 159 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014605" column at position 160 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014605" column at position 161 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014605" column at position 162 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014605" column at position 163 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014605" column at position 164 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014605" column at position 165 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014605" column at position 166 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014605" column at position 167 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014605" column at position 168 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014605" column at position 169 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014605" column at position 170 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014605" column at position 171 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014610" column at position 172 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014610" column at position 173 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014610" column at position 174 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014610" column at position 175 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014610" column at position 176 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014610" column at position 177 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014610" column at position 178 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014610" column at position 179 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014610" column at position 180 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014610" column at position 181 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014610" column at position 182 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014610" column at position 183 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014610" column at position 184 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014610" column at position 185 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014610" column at position 186 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014610" column at position 187 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014610" column at position 188 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014611" column at position 189 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014611" column at position 190 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014611" column at position 191 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014611" column at position 192 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014611" column at position 193 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014611" column at position 194 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014611" column at position 195 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014611" column at position 196 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014611" column at position 197 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014611" column at position 198 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014611" column at position 199 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014611" column at position 200 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014611" column at position 201 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014611" column at position 202 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014611" column at position 203 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014611" column at position 204 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014611" column at position 205 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014612" column at position 206 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014612" column at position 207 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014612" column at position 208 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014612" column at position 209 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014612" column at position 210 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014612" column at position 211 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014612" column at position 212 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014612" column at position 213 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014612" column at position 214 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014612" column at position 215 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014612" column at position 216 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014612" column at position 217 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014612" column at position 218 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014612" column at position 219 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014612" column at position 220 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014612" column at position 221 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014612" column at position 222 in the MS_METABOLITE_DATA table has all null values. Warning: The "S00014613" column at position 223 in the MS_METABOLITE_DATA table has all null values. Warning: The 2nd "S00014613" column at position 224 in the MS_METABOLITE_DATA table has all null values. Warning: The 3rd "S00014613" column at position 225 in the MS_METABOLITE_DATA table has all null values. Warning: The 4th "S00014613" column at position 226 in the MS_METABOLITE_DATA table has all null values. Warning: The 5th "S00014613" column at position 227 in the MS_METABOLITE_DATA table has all null values. Warning: The 6th "S00014613" column at position 228 in the MS_METABOLITE_DATA table has all null values. Warning: The 7th "S00014613" column at position 229 in the MS_METABOLITE_DATA table has all null values. Warning: The 8th "S00014613" column at position 230 in the MS_METABOLITE_DATA table has all null values. Warning: The 9th "S00014613" column at position 231 in the MS_METABOLITE_DATA table has all null values. Warning: The 10th "S00014613" column at position 232 in the MS_METABOLITE_DATA table has all null values. Warning: The 11th "S00014613" column at position 233 in the MS_METABOLITE_DATA table has all null values. Warning: The 12th "S00014613" column at position 234 in the MS_METABOLITE_DATA table has all null values. Warning: The 13th "S00014613" column at position 235 in the MS_METABOLITE_DATA table has all null values. Warning: The 14th "S00014613" column at position 236 in the MS_METABOLITE_DATA table has all null values. Warning: The 15th "S00014613" column at position 237 in the MS_METABOLITE_DATA table has all null values. Warning: The 16th "S00014613" column at position 238 in the MS_METABOLITE_DATA table has all null values. Warning: The 17th "S00014613" column at position 239 in the MS_METABOLITE_DATA table has all null values. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.