Validation Log
2025-12-14 21:13:59.895029
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000346/mwtab/txt
Study ID:      ST000231
Analysis ID:   AN000346
File format:   txt
Status: Contains Validation Issues
Number of Issues: 24

Number of Warnings: 10

Number of Value Errors: 15

Number of Consistency Errors: 2

Number of Format Errors: 5

Issue Log:
Error: An empty value or a null value was detected for the subsection, "COLLECTION_SUMMARY", in the "COLLECTION" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether.
Error: An empty value or a null value was detected for the subsection, "CHROMATOGRAPHY_TYPE", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "INSTRUMENT_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: An empty value or a null value was detected for the subsection, "COLUMN_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section  is missing.
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"1-(5^-Phosphoribosyl)-5-amino-4-(N-succinocarboxamide)-imidazole(-9.33)/"
	"5^-Deoxy-5^-methylthioadenosine"
	"Pantetheine 4^-phosphate(-1.53)/"
	"Pyridoxamine 5^-phosphate"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"1-(5'-Phosphoribosyl)-5-amino-4-(N-succinocarboxamide)-imidazole(-9.33)/"
	"5'-Deoxy-5'-methylthioadenosine"
	"Pantetheine 4'-phosphate(-1.53)/"
	"Pyridoxamine 5'-phosphate"
Warning: The "ri" column at position 3 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 4 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "other_id" and "other_id_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "moverz_quant" column at position 2 in the METABOLITES table has all null values.
Warning: The "ri" column at position 3 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 4 in the METABOLITES table has all null values.
Warning: The "pubchem_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 6 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 8 in the METABOLITES table has all null values.