Validation Log 2025-12-14 21:19:09.857034 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000406/mwtab/json Study ID: ST000257 Analysis ID: AN000406 File format: json Status: Contains Validation Issues Number of Issues: 67 Number of Warnings: 55 Number of Value Errors: 63 Number of Consistency Errors: 2 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["COLLECTION"]["COLLECTION_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value, "See protocol file", in ["MS"]["CAPILLARY_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "Negative", in ["MS"]["CAPILLARY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["CHROMATOGRAPHY_TYPE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["COLUMN_NAME"]. A legitimate value should be provided for this required key. Error: The value, "0.25", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "5 L", in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "600 L", in ["CHROMATOGRAPHY"]["WEAK_WASH_VOLUME"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "600 L", in ["CHROMATOGRAPHY"]["STRONG_WASH_VOLUME"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "17 L", in ["CHROMATOGRAPHY"]["SAMPLE_LOOP_SIZE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "11_12_15-THET" "11_12-DiHETrE_1" "12_13-DiHODE_1" "12_13-DiHOME_1" "14_15-DiHETE_1" "14_15-DiHETrE_1" "15_16-DiHODE_1" "17_18-DiHETE_1" "19_20-DiHDoPA_1" "5_15-DiHETE_1" "5_6-DiHETrE_1" "8_15-DiHETE_1" "8_9-DiHETrE_1" "9_10-DiHODE_1" "9_10-DiHOME_1" "9_12_13-TriHOME_1" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "11,12,15-THET" "11,12-DiHETrE" "12,13-DiHODE" "12,13-DiHOME" "14,15-DiHETE" "14,15-DiHETrE" "15,16-DiHODE" "17,18-DiHETE" "19,20-DiHDoPA" "5,15-DiHETE" "5,6-DiHETrE" "8,15-DiHETE" "8,9-DiHETrE" "9,10-DiHODE" "9,10-DiHOME" "9,12,13-TriHOME" Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "other_id" and "other_id_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "LF liv 6" column at position 47 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF liv 7" column at position 48 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF liv 8" column at position 49 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF mus 1" column at position 50 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF mus 2" column at position 51 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF mus 3" column at position 52 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF mus 6" column at position 53 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF mus 7" column at position 54 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF mus 8" column at position 55 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF plasma 1" column at position 56 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF plasma 2" column at position 57 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF plasma 3" column at position 58 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF plasma 6" column at position 59 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF plasma 7" column at position 60 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "LF plasma 8" column at position 61 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW epi 2" column at position 62 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW epi 3" column at position 63 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW epi 4" column at position 64 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW epi 5" column at position 65 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW epi 7" column at position 66 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW epi 8" column at position 67 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW Hypo 2" column at position 68 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW Hypo 3" column at position 69 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW Hypo 4" column at position 70 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW Hypo 5" column at position 71 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW Hypo 7" column at position 72 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW Hypo 8" column at position 73 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW liv 2" column at position 74 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW liv 3" column at position 75 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW liv 4" column at position 76 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW liv 5" column at position 77 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW liv 7" column at position 78 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW liv 8" column at position 79 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW mus 2" column at position 80 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW mus 3" column at position 81 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW mus 4" column at position 82 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW mus 5" column at position 83 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW mus 7" column at position 84 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW mus 8" column at position 85 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW plasma 2" column at position 86 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW plasma 3" column at position 87 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW plasma 4" column at position 88 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW plasma 5" column at position 89 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW plasma 7" column at position 90 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "SW plasma 8" column at position 91 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "moverz_quant" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.