Validation Log 2025-12-14 21:19:21.824811 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000410/mwtab/txt Study ID: ST000258 Analysis ID: AN000410 File format: txt Status: Contains Validation Issues Number of Issues: 17 Number of Warnings: 7 Number of Value Errors: 10 Number of Consistency Errors: 2 Number of Format Errors: 3 Issue Log: Error: The required property, "COLLECTION_SUMMARY", in the "COLLECTION" section is missing. Error: An empty value or a null value was detected for the subsection, "ANIMAL_ENDP_CLINICAL_SIGNS", in the "TREATMENT" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The required property, "TREATMENT_SUMMARY", in the "TREATMENT" section is missing. Error: The required property, "SAMPLEPREP_SUMMARY", in the "SAMPLEPREP" section is missing. Error: The value, "250ºC", for the subsection, "DRY_GAS_TEMP", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "200 ?L/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "40C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "2 ?L", for the subsection, "SAMPLE_INJECTION", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "ADP_ Na-2H adduct" "glucose_ Cl adduct" "L-2_3-Dihydrodipicolinate" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "ADP, Na-2H adduct" "glucose, Cl adduct" "L-2,3-Dihydrodipicolinate" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "other_id" and "other_id_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.