Validation Log 2025-12-14 21:31:02.901710 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000600/mwtab/txt Study ID: ST000367 Analysis ID: AN000600 File format: txt Status: Contains Validation Issues Number of Issues: 13 Number of Warnings: 5 Number of Value Errors: 8 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected for the subsection, "PHONE", in the "STUDY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLUMN_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: The following metabolites in the METABOLITES table appear more than once in the table: "(S)-Methylmalonic acid semialdehyde-13C3[-H+]-" "(S)-Methylmalonic acid semialdehyde-13C4[-H+]-" "CMP-13C0[-H+]-" "CMP-13C5[-H+]-" Warning: The "corrected_mz" column at position 4 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention_time(min)" column at position 8 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "assignment%method" column at position 2 in the METABOLITES table, matches a standard column name, "assignment_method". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "isotopologue%type" column at position 7 in the METABOLITES table, matches a standard column name, "isotopologue_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.