Validation Log 2025-12-14 21:54:49.400243 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000824/mwtab/json Study ID: ST000542 Analysis ID: AN000824 File format: json Status: Contains Validation Issues Number of Issues: 32 Number of Warnings: 26 Number of Value Errors: 26 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected in ["MS"]["MS_COMMENTS"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing. Warning: The "quantified m/z" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem ID" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG ID" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention index" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "retention index" was found in the ["MS_METABOLITE_DATA"]["Metabolites"] table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found. Warning: The "1A-180" column at position 2 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "1A-480" column at position 3 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "2A-180" column at position 6 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "3A-180" column at position 10 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "3A-480" column at position 11 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "5A-180" column at position 14 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "5A-480" column at position 15 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "8A-180" column at position 22 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "14A-180" column at position 26 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "14A-480" column at position 27 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "14B-180" column at position 28 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "14B-480" column at position 29 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "16B-180" column at position 34 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "16B-480" column at position 35 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "16C-480" column at position 37 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "18A-180" column at position 38 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "19A-180" column at position 42 in the ["MS_METABOLITE_DATA"]["Data"] table has all null values. Warning: The "retention index" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "quantified m/z" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "PubChem ID" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "KEGG ID" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.