Validation Log 2025-12-14 21:55:05.948114 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000830/mwtab/json Study ID: ST000545 Analysis ID: AN000830 File format: json Status: Contains Validation Issues Number of Issues: 11 Number of Warnings: 0 Number of Value Errors: 6 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: The value, "Medium", in ["MS"]["COLLISION_GAS"] should be one of "Nitrogen" or "Argon". Ignore this when more complicated descriptions are required. Error: The value, "5500", in ["MS"]["ION_SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "20uL", in ["CHROMATOGRAPHY"]["SAMPLE_INJECTION"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "3.0 minutes", in ["CHROMATOGRAPHY"]["ANALYTICAL_TIME"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['min']. Ignore this when more complicated descriptions are required. Error: The value, "10 degrees C", in ["CHROMATOGRAPHY"]["TARGET_SAMPLE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "100uL", in ["CHROMATOGRAPHY"]["SAMPLE_LOOP_SIZE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The ["MS_METABOLITE_DATA"]["Metabolites"] table does not have a column for "Metabolite". It is likely misspelled or using a common incorrect substitute.