Validation Log 2025-12-14 21:55:07.328396 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000831/mwtab/txt Study ID: ST000545 Analysis ID: AN000831 File format: txt Status: Contains Validation Issues Number of Issues: 13 Number of Warnings: 0 Number of Value Errors: 7 Number of Consistency Errors: 2 Number of Format Errors: 4 Issue Log: Error: The value, "Medium", for the subsection, "COLLISION_GAS", in the "MS" section should be one of "Nitrogen" or "Argon". Ignore this when more complicated descriptions are required. Error: The value, "-4500", for the subsection, "ION_SPRAY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "20uL", for the subsection, "SAMPLE_INJECTION", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "3.0 minutes", for the subsection, "ANALYTICAL_TIME", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['min']. Ignore this when more complicated descriptions are required. Error: The value, "10 degrees C", for the subsection, "TARGET_SAMPLE_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "100uL", for the subsection, "SAMPLE_LOOP_SIZE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: SUBJECT_SAMPLE_FACTORS section missing sample ID(s). The following IDs were found in the MS_METABOLITE_DATA section but not in the SUBJECT_SAMPLE_FACTORS: "" Error: Column(s) with no name were found in the MS_METABOLITE_DATA table. Error: The section, MS_METABOLITE_DATA, has a mismatch between the number of headers and the number of elements in each line. Either a line(s) has more values than headers or there are too few headers.