Validation Log 2025-12-14 21:55:11.318452 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN000832/mwtab/json Study ID: ST000546 Analysis ID: AN000832 File format: json Status: Contains Validation Issues Number of Issues: 18 Number of Warnings: 7 Number of Value Errors: 17 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected in ["PROJECT"]["PROJECT_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["PROJECT"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["STUDY"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["COLLECTION"]["COLLECTION_SUMMARY"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value, "300°C", in ["MS"]["CAPILLARY_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "+50 V", in ["MS"]["CAPILLARY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["MS"]["FRAGMENTATION_METHOD"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "4kV", in ["MS"]["SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['kV']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["MS"]["MS_COMMENTS"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "25°C", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Warning: The "quantified m/z" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem CID" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG ID" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention index" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "retention index" was found in the ["MS_METABOLITE_DATA"]["Metabolites"] table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found. Warning: The "quantified m/z" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "PubChem CID" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.