Validation Log 2025-12-14 22:29:57.128537 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001443/mwtab/json Study ID: ST000886 Analysis ID: AN001443 File format: json Status: Contains Validation Issues Number of Issues: 20 Number of Warnings: 10 Number of Value Errors: 13 Number of Consistency Errors: 2 Number of Format Errors: 3 Issue Log: Error: An empty value or a null value was detected in ["PROJECT"]["PHONE"]. A legitimate value should be provided for this required key. Error: An empty value or a null value was detected in ["COLLECTION"]["COLLECTION_SUMMARY"]. A legitimate value should be provided for this required key. Error: The value in ["TREATMENT"]["PLANT_TEMP"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The required property, "TREATMENT_SUMMARY", in ["TREATMENT"] is missing. Error: The value, "350ul/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing. Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table: "1_2-Benzisothiazolin-3-one" "3_4-DIHYDROXY-L-PHENYLALANINE_R1" "3_4-DIHYDROXY-L-PHENYLALANINE_R2" "3^-CMP" "5^-DEOXYADENOSINE" "LL-2_6-DIAMINOHEPTANEDIOATE" "Tryptophan-2_3_3-D3" Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table: "1,2-Benzisothiazolin-3-one" "3,4-DIHYDROXY-L-PHENYLALANINE_R1" "3,4-DIHYDROXY-L-PHENYLALANINE_R2" "3'-CMP" "5'-DEOXYADENOSINE" "LL-2,6-DIAMINOHEPTANEDIOATE" "Tryptophan-2,3,3-D3" Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table. Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.