Validation Log 2026-02-08 02:52:26.864297 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001602/mwtab/txt Study ID: ST000978 Analysis ID: AN001602 File format: txt Status: Contains Validation Issues Number of Issues: 45 Number of Warnings: 27 Number of Value Errors: 39 Number of Consistency Errors: 0 Number of Format Errors: 3 Issue Log: Error: The value, ">30", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: The value, "Male and female", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "TREATMENT_SUMMARY", in the "TREATMENT" section. A legitimate value should be provided for this required subsection. Error: The value, "0.736ml/min", for the subsection, "HELIUM_FLOW", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['mL/min']. Ignore this when more complicated descriptions are required. Error: The value, "70ev", for the subsection, "IONIZATION_ENERGY", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['eV']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "0.736ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "1uL", for the subsection, "SAMPLE_INJECTION", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "250C", for the subsection, "INJECTION_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Error: The value, "37 minutes", for the subsection, "ANALYTICAL_TIME", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['min']. Ignore this when more complicated descriptions are required. Error: The value, "70eV", for the subsection, "CAPILLARY_VOLTAGE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "3x 5uL", for the subsection, "WEAK_WASH_VOLUME", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "3x 5uL", for the subsection, "STRONG_WASH_VOLUME", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The value, "10uL", for the subsection, "SAMPLE_SYRINGE_SIZE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: The "quantified m/z" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem CID" column at position 4 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG ID" column at position 5 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Local ID" column at position 8 in the METABOLITES table, matches a standard column name, "other_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention index" column at position 2 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "Local ID" was found in the METABOLITES table, but this column implies that another column, "other_id_type", should also exist, and that column was not found. Warning: The column "retention index" was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found. Warning: The standard column, "other_id", was found in the METABOLITES table as "Local ID". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "121" column at position 120 in the MS_METABOLITE_DATA table has all null values. Warning: The "122" column at position 121 in the MS_METABOLITE_DATA table has all null values. Warning: The "143" column at position 142 in the MS_METABOLITE_DATA table has all null values. Warning: The "149" column at position 148 in the MS_METABOLITE_DATA table has all null values. Warning: The "246" column at position 245 in the MS_METABOLITE_DATA table has all null values. Warning: The "294" column at position 292 in the MS_METABOLITE_DATA table has all null values. Warning: The "296" column at position 294 in the MS_METABOLITE_DATA table has all null values. Warning: The "297" column at position 295 in the MS_METABOLITE_DATA table has all null values. Warning: The "312" column at position 310 in the MS_METABOLITE_DATA table has all null values. Warning: The "121" column at position 120 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "122" column at position 121 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "143" column at position 142 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "149" column at position 148 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "246" column at position 245 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "294" column at position 292 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "296" column at position 294 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "297" column at position 295 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "312" column at position 310 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "quantified m/z" column at position 3 in the METABOLITES table has all null values.