Validation Log 2025-12-14 22:44:29.208053 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001703/mwtab/txt Study ID: ST001040 Analysis ID: AN001703 File format: txt Status: Contains Validation Issues Number of Issues: 11 Number of Warnings: 7 Number of Value Errors: 10 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "250C", for the subsection, "CAPILLARY_TEMPERATURE", in the "MS" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "-3000", for the subsection, "CAPILLARY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "50C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Warning: The "mz" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Adduct" column at position 5 in the METABOLITES table, matches a standard column name, "adduct", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 36 m-H / (m+HCOO)- 53 m-H / (m+HCOO)+[-H2O] Warning: The "RT (min)" column at position 2 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT (sec)" column at position 4 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "matrix_1" column at position 7 in the MS_METABOLITE_DATA table has all null values. Warning: The "matrix_2" column at position 8 in the MS_METABOLITE_DATA table has all null values. Warning: The "matrix_3" column at position 9 in the MS_METABOLITE_DATA table has all null values.