Validation Log 2025-12-14 22:44:41.097847 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001709/mwtab/txt Study ID: ST001045 Analysis ID: AN001709 File format: txt Status: Contains Validation Issues Number of Issues: 14 Number of Warnings: 9 Number of Value Errors: 9 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "protocol.id" "replicate" Warning: The "isotopologue%type" column at position 4 in the METABOLITES table, matches a standard column name, "isotopologue_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.