Validation Log 2025-12-14 22:44:52.187160 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001716/mwtab/txt Study ID: ST001048 Analysis ID: AN001716 File format: txt Status: Contains Validation Issues Number of Issues: 25 Number of Warnings: 21 Number of Value Errors: 24 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "250C", for the subsection, "CAPILLARY_TEMPERATURE", in the "MS" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "3000", for the subsection, "CAPILLARY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "25C", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Warning: The "mz" column at position 2 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT_sec" column at position 3 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "RT_min" column at position 6 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Matrix_Blank_b1_014" column at position 2 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b1_015" column at position 3 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b1_016" column at position 4 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b1_106" column at position 88 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b1_107" column at position 89 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b1_108" column at position 90 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b2_014" column at position 91 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b2_015" column at position 92 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b2_016" column at position 93 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b2_106" column at position 177 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b2_107" column at position 178 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b2_108" column at position 179 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b3_014" column at position 180 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b3_015" column at position 181 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b3_016" column at position 182 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b3_071" column at position 231 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b3_072" column at position 232 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Matrix_Blank_b3_073" column at position 233 in the MS_METABOLITE_DATA table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.