Validation Log 2025-12-14 22:07:15.929215 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001820/mwtab/txt Study ID: ST000623 Analysis ID: AN001820 File format: txt Status: Contains Validation Issues Number of Issues: 10 Number of Warnings: 0 Number of Value Errors: 2 Number of Consistency Errors: 3 Number of Format Errors: 5 Issue Log: Error: The value, "POSITIVE POSITIVE", for the subsection, "ION_MODE", in the "MS" section should be one of "Positive", "Negative", "Positive, Negative", or "Unspecified". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Error: The section, MS, has a sub-section, INSTRUMENT_TYPE, that is duplicated. Error: The section, MS, has a sub-section, MS_TYPE, that is duplicated. Error: The section, MS, has a sub-section, ION_MODE, that is duplicated.