Validation Log
2025-12-14 22:50:24.335386
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001866/mwtab/txt
Study ID:      ST001129
Analysis ID:   AN001866
File format:   txt
Status: Contains Validation Issues
Number of Issues: 21

Number of Warnings: 17

Number of Value Errors: 17

Number of Consistency Errors: 2

Number of Format Errors: 1

Issue Log:
Error: The value, "15 celsius", for the subsection, "TEMPERATURE", in the "NM" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C', 'K']. Ignore this when more complicated descriptions are required.
Error: Unknown or invalid section, "CHROMATOGRAPHY".
Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data:
	"cell_type"
	"protocol.id"
	"replicate"
	"protocol.id"
	"type"
Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data:
	"cell_type"
	"protocol.id"
	"replicate"
	"protocol.id"
	"type"
Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data:
	"cell_type"
	"protocol.id"
	"replicate"
	"protocol.id"
	"type"
Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data:
	"cell_type"
	"protocol.id"
	"replicate"
	"protocol.id"
	"type"
Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data:
	"cell_type"
	"protocol.id"
	"replicate"
	"protocol.id"
	"type"
Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data:
	"cell_type"
	"protocol.id"
	"replicate"
	"protocol.id"
	"type"
Error: The following metabolites in the, NMR_METABOLITE_DATA table were not found in the METABOLITES table:
	"AXP-1^_1"
	"AXP-1^ 13C-B_1"
	"AXP-1^_2"
	"AXP-1^_3"
	"AXP-1^_4"
	"m-Ins-1_3_1"
	"m-Ins-1_3_2"
	"m-Ins-1_3_3"
	"m-Ins-1_3_4"
	"NAD+-A1^_1"
	"NAD+-A1^ 13C-A_1"
	"NAD+-A1^ 13C-B_1"
	"NAD+-A1^_2"
	"NAD+-N1^_1"
	"NAD+-N1^ 13C-A_1"
	"NAD+-N1^ 13C-B_1"
	"NAD+-N1^_2"
	"Phe-2_6_1"
	"Phe-2_6_2"
	"Phe-3_5_1"
	"Phe-3_5_2"
	"Phe-3_5_3"
	"Succinate-2_3_1"
	"Tyr-2_6_1"
	"Tyr-2_6_2"
	"Tyr-3_5_1"
	"Tyr-3_5_2"
	"UXP-1^_1"
	"UXP-1^ 13C-A_1"
	"UXP-1^ 13C-B_1"
	"UXP-1^_2"
	"UXP-1^_3"
Error: The following metabolites in the METABOLITES table were not found in the NMR_METABOLITE_DATA table:
	"AXP-1'_1"
	"AXP-1' 13C-B_1"
	"AXP-1'_2"
	"AXP-1'_3"
	"AXP-1'_4"
	"m-Ins-1,3_1"
	"m-Ins-1,3_2"
	"m-Ins-1,3_3"
	"m-Ins-1,3_4"
	"NAD+-A1'_1"
	"NAD+-A1' 13C-A_1"
	"NAD+-A1' 13C-B_1"
	"NAD+-A1'_2"
	"NAD+-N1'_1"
	"NAD+-N1' 13C-A_1"
	"NAD+-N1' 13C-B_1"
	"NAD+-N1'_2"
	"Phe-2,6_1"
	"Phe-2,6_2"
	"Phe-3,5_1"
	"Phe-3,5_2"
	"Phe-3,5_3"
	"Succinate-2,3_1"
	"Tyr-2,6_1"
	"Tyr-2,6_2"
	"Tyr-3,5_1"
	"Tyr-3,5_2"
	"UXP-1'_1"
	"UXP-1' 13C-A_1"
	"UXP-1' 13C-B_1"
	"UXP-1'_2"
	"UXP-1'_3"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri" column at position 7 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.
Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.