Validation Log 2025-12-14 22:50:54.876234 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001869/mwtab/txt Study ID: ST001139 Analysis ID: AN001869 File format: txt Status: Contains Validation Issues Number of Issues: 19 Number of Warnings: 17 Number of Value Errors: 17 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "15 celsius", for the subsection, "TEMPERATURE", in the "NM" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C', 'K']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid section, "CHROMATOGRAPHY". Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "replicate" "protocol.id" "type" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "replicate" "protocol.id" "type" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "replicate" "protocol.id" "type" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "replicate" "protocol.id" "type" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "replicate" "protocol.id" "type" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "cell_type" "protocol.id" "replicate" "protocol.id" "type" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "pubchem_id" column at position 2 in the METABOLITES table has all null values. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "kegg_id" column at position 4 in the METABOLITES table has all null values. Warning: The "other_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.