Validation Log 2025-12-14 22:52:36.409356 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN001903/mwtab/txt Study ID: ST001153 Analysis ID: AN001903 File format: txt Status: Contains Validation Issues Number of Issues: 17 Number of Warnings: 12 Number of Value Errors: 9 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: The "SUPER_PATHWAY" column at position 2 in the METABOLITES table, matches a standard column name, "pathway". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "SUB_PATHWAY" column at position 3 in the METABOLITES table, matches a standard column name, "pathway". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PubChem ID" column at position 9 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG ID" column at position 10 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB" column at position 11 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS" column at position 8 in the METABOLITES table, matches a standard column name, "cas_number". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "CAS" column at position 8 in the METABOLITES table, matches a standard column name, "cas_number", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 56-41-7; 1 56-41-7;107-95-9; 2 3025-95-4; 3 1492-24-6; 4 57-00-1; 5 60-27-5; 6 3347-90-8; 7 52-90-4;56-89-3; 8 454-29-5; 9 63-68-3; 10 65-82-7; 11 107-35-7; 12 56-86-0; 13 56-85-9; 14 98-79-3; 15 13081-14-6; 16 103239-24-3; 17 70-18-8; 18 495-27-2; 19 107-43-7; 20 1118-68-9; 21 56-40-6; 22 543-24-8; 23 107-97-1; 24 56-45-1; 25 72-19-5; 26 5934-29-2; 27 542-32-5;1118-90-7; 28 56-87-1; 29 23284-33-5; 30 4043-87-2; 31 938-96-5; 32 6482-98-0; 33 501-52-0; 34 2018-61-3; 35 937-34-8; 36 500-98-1; 37 63-91-2; 38 60-18-4; 39 2457-80-9; 40 124-20-9; 41 2642-37-7; 43 2922-83-0; 44 1218-34-4; 45 153-98-0; 46 73-22-3; 47 1119-34-2; 48 372-75-8; 49 1190-49-4; 50 6205-08-9; 51 3184-13-2; 52 147-85-3; 53 51-35-4; 54 57-13-6; 55 31023-25-3; 56 3715-29-5; 57 51829-07-3; 58 816-66-0; 59 600-37-3; 60 625-08-1; 61 99159-87-2; 62 25518-49-4; 63 73-32-5; 65 16284-60-9; 66 61-90-5; 67 1188-21-2; 68 72-18-4; 69 13752-84-6; 70 131-48-6; 71 57-48-7; 72 3458-28-4; 73 154-58-5; 74 102783-53-9; 75 80731-10-8; 76 102783-56-2; 77 50-99-7; 78 600-19-1; 80 79-33-4; 81 10526-80-4; 82 127-17-3; 83 70753-61-6; 84 14875-96-8; 85 68414-18-6; 86 98-92-0; 87 6138-41-6 ; 88 137-08-6; 89 59-02-9;10191-41-0; 90 585-84-2; 91 77-92-9; 92 100-17-8; 93 6915-15-7; 94 110-15-6; 96 94249-01-1; 97 7664-38-2 ; 98 1466-09-3; 99 2393-58-0; 100 81-25-4; 102 145-42-6; 103 207737-97-1; 104 14605-22-2; 105 10457-99-5; 106 5080-50-2; 107 461-05-2; 108 6249-56-5; 109 6920-35-0; 110 3671-77-0; 112 81187-21-5; 113 73837-14-6; 115 6217-54-5; 116 2234-74-4 ; 117 10-2005-9;10417-94-4; 118 60-33-3; 120 24003-67-6; 121 25576-40-3; 122 20208-73-5 ; 123 17298-37-2 ; 125 2724-59-6; 127 123-99-9; 129 629-22-1; 130 67-48-1; 131 141-43-5; 132 29849-82-9; 133 28319-77-9; 134 1071-23-4; 135 643-12-9; 136 87-89-8; 137 10284-63-6; 138 57-55-6; 139 625-72-9; 140 29743-97-3; 141 73033-09-7; 142 2091-25-0; 143 506-32-1; 144 2091-39-6; 146 506-12-7; 147 544-63-8; 148 544-64-9 ; 149 646-30-0; 150 112-80-1; 151 57-10-3; 152 373-49-9; 153 57-11-4; 154 111174-40-4 ; 161 19420-56-5; 165 17364-16-8; 169 19420-57-6; 170 69747-55-3; 178 112-37-8; 179 142-62-1; 180 124-07-2; 181 111-14-8; 182 143-07-7; 183 112-05-0; 184 123-94-4; 186 474-62-4; 187 57-88-5; 188 7023-27-0; 189 4691-65-0; 190 20398-34-9; 191 149022-20-8; 192 5550-12-9; 193 97-59-6; 194 69-93-2;120K5305; 195 50887-69-9; 196 1445-07-4; 197 66-22-8; 198 58-96-8; 199 1948-31-8; 201 2566-39-4; 202 7432-24-8; 203 5652-48-2; 204 7432-23-7; 205 2746-34-1; 206 65-85-0; 207 495-69-2; 208 819-83-0; 209 79-14-1; 210 142-73-4; 212 60-00-4; 214 58511-63-0; 215 1195-94-4; 216 4136-37-2; 217 149-32-6; Warning: The "COMP_ID" column at position 4 in the METABOLITES table, matches a standard column name, "other_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention index" column at position 6 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The column "COMP_ID" was found in the METABOLITES table, but this column implies that another column, "other_id_type", should also exist, and that column was not found. Warning: The column "retention index" was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found. Warning: The standard column, "other_id", was found in the METABOLITES table as "COMP_ID". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.