Validation Log 2025-12-14 22:45:28.520791 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN002145/mwtab/json Study ID: ST001056 Analysis ID: AN002145 File format: json Status: Contains Validation Issues Number of Issues: 25 Number of Warnings: 1 Number of Value Errors: 20 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: An empty value or a null value was detected in ["PROJECT"]["PROJECT_COMMENTS"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "Not applicable", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["COLLECTION"]["ADDITIVES"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "Time (0, 6, 12, 24, 48, 96 h)", in ["TREATMENT"]["TREATMENT_DOSEDURATION"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['h', 'weeks', 'days']. Ignore this when more complicated descriptions are required. Error: The value, "25°C", in ["TREATMENT"]["PLANT_TEMP"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLEPREP_PROTOCOL_ID"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLEPREP_PROTOCOL_FILENAME"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SAMPLEPREP_PROTOCOL_COMMENTS"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["EXTRACT_ENRICHMENT"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["EXTRACT_CLEANUP"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: An empty value or a null value was detected in ["SAMPLEPREP"]["SUBCELLULAR_LOCATION"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "1 ml/min", in ["MS"]["HELIUM_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['mL/min']. Ignore this when more complicated descriptions are required. Error: The value, "260", in ["MS"]["ION_SOURCE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "260", in ["MS"]["SOURCE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid subsection, "ACQUISITION_DATE", in ["MS"]. Error: The value, "1 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected in ["CHROMATOGRAPHY"]["METHODS_ID"]. Either a legitimate value should be provided for this key, or it should be removed altogether. Error: The value, "250", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Error: The value, "250", in ["CHROMATOGRAPHY"]["TRANSFERLINE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing. Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing. Warning: The "12HUKR3" column at position 13 in the ["MS_METABOLITE_DATA"]["Data"] table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Error: The ["MS_METABOLITE_DATA"]["Metabolites"] table does not have a column for "Metabolite". It is likely misspelled or using a common incorrect substitute.