Validation Log 2025-12-14 23:08:19.607676 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN002206/mwtab/txt Study ID: ST001325 Analysis ID: AN002206 File format: txt Status: Contains Validation Issues Number of Issues: 28 Number of Warnings: 23 Number of Value Errors: 23 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: The "quantitated m/z" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Neutral Mass" column at position 6 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Delta Mass" column at position 9 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Derived Molecular Mass" column at position 26 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Average Mass" column at position 32 in the METABOLITES table, matches a standard column name, "mass". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "super_class" column at position 10 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "main_class" column at position 11 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "sub_class" column at position 12 in the METABOLITES table, matches a standard column name, "class". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Adduct/NL" column at position 28 in the METABOLITES table, matches a standard column name, "adduct". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "PUBCHEM ID" column at position 18 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGG ID" column at position 16 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDB" column at position 13 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "lipidmaps_id" column at position 19 in the METABOLITES table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "chebi" column at position 17 in the METABOLITES table, matches a standard column name, "chebi_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Retention times" column at position 4 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Library RT" column at position 7 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Delta RT" column at position 8 in the METABOLITES table, matches a standard column name, "delta_rt". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "Adduct/NL" column at position 28 in the METABOLITES table has all null values. Warning: The "named" column at position 21 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Charge Carrier" column at position 27 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Match Replicate" column at position 29 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Redundancy Group" column at position 30 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different. Warning: The "Group Size" column at position 31 in the METABOLITES table may have incorrect values. 90% or more of the values are the same, but 10% or less are different.