Validation Log 2025-12-14 23:19:27.769081 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN002416/mwtab/json Study ID: ST001445 Analysis ID: AN002416 File format: json Status: Contains Validation Issues Number of Issues: 33 Number of Warnings: 27 Number of Value Errors: 28 Number of Consistency Errors: 2 Number of Format Errors: 2 Issue Log: Error: The required property, "PROJECT_SUMMARY", in ["PROJECT"] is missing. Error: The value, "15 celsius", in ["NM"]["TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C', 'K']. Ignore this when more complicated descriptions are required. Error: Unknown or invalid section, "CHROMATOGRAPHY". Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "replicate" "protocol.id" Error: The following metabolites in the, ["NMR_METABOLITE_DATA"]["Data"] table were not found in the ["NMR_METABOLITE_DATA"]["Metabolites"] table: "AXP-1^_1" "AXP-1^ 13C-A_1" "AXP-1^ 13C-A_2" "AXP-1^ 13C-B_1" "AXP-1^_2" "AXP-1^_3" "AXP-1^_4" "AXP-1^_5" "GXP-1^_1" "GXP-1^_2" "Inosine-1^_1" "Inosine-1^_2" "m-Ins-1_3_1" "m-Ins-1_3_2" "m-Ins-1_3_3" "m-Ins-1_3_4" "NAD+-A1^_1" "NAD+-A1^_2" "NAD+-A1^_3" "NAD+-N1^_1" "NAD+-N1^ 13C-B_1" "NAD+-N1^_2" "Phe-2_6_1" "Phe-2_6_2" "Phe-3_5_1" "Phe-3_5_2" "Phe-3_5_3" "Succinate-2_3_1" "Tyr-2_6_1" "Tyr-2_6_2" "Tyr-3_5_1" "Tyr-3_5_2" "UXP-1^_1" "UXP-1^_2" Error: The following metabolites in the ["NMR_METABOLITE_DATA"]["Metabolites"] table were not found in the ["NMR_METABOLITE_DATA"]["Data"] table: "AXP-1'_1" "AXP-1' 13C-A_1" "AXP-1' 13C-A_2" "AXP-1' 13C-B_1" "AXP-1'_2" "AXP-1'_3" "AXP-1'_4" "AXP-1'_5" "GXP-1'_1" "GXP-1'_2" "Inosine-1'_1" "Inosine-1'_2" "m-Ins-1,3_1" "m-Ins-1,3_2" "m-Ins-1,3_3" "m-Ins-1,3_4" "NAD+-A1'_1" "NAD+-A1'_2" "NAD+-A1'_3" "NAD+-N1'_1" "NAD+-N1' 13C-B_1" "NAD+-N1'_2" "Phe-2,6_1" "Phe-2,6_2" "Phe-3,5_1" "Phe-3,5_2" "Phe-3,5_3" "Succinate-2,3_1" "Tyr-2,6_1" "Tyr-2,6_2" "Tyr-3,5_1" "Tyr-3,5_2" "UXP-1'_1" "UXP-1'_2" Warning: The "ri" column at position 7 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Error: Column(s) with no name were found in the ["NMR_METABOLITE_DATA"]["Metabolites"] table. Warning: The "pubchem_id" column at position 2 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "inchi_key" column at position 3 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "kegg_id" column at position 4 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id" column at position 5 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "other_id_type" column at position 6 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri" column at position 7 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "ri_type" column at position 8 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "moverz_quant" column at position 9 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values. Warning: The "" column at position 10 in the ["NMR_METABOLITE_DATA"]["Metabolites"] table has all null values.