Validation Log 2025-12-14 23:19:54.677246 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN002420/mwtab/txt Study ID: ST001449 Analysis ID: AN002420 File format: txt Status: Contains Validation Issues Number of Issues: 28 Number of Warnings: 19 Number of Value Errors: 23 Number of Consistency Errors: 0 Number of Format Errors: 5 Issue Log: Error: The value, "000000", for "PROJECT_ID" in the file header must be the letters "PR" followed by 6 numbers. Ex. "PR001405". Error: An empty value or a null value was detected for the subsection, "CHROMATOGRAPHY_SUMMARY", in the "CHROMATOGRAPHY" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "INSTRUMENT_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: An empty value or a null value was detected for the subsection, "COLUMN_NAME", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data: "protocol.id" "protocol.id" "protocol.id" Warning: The "adducted_elemental_formula" column at position 2 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "adducted_isotopic_formula" column at position 3 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "elemental_formula" column at position 5 in the METABOLITES table, matches a standard column name, "formula". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "isotopologue%type" column at position 7 in the METABOLITES table, matches a standard column name, "isotopologue_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.