Validation Log
2025-12-14 23:29:30.580659
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN002669/mwtab/json
Study ID:      ST001633
Analysis ID:   AN002669
File format:   json
Status: Contains Validation Issues
Number of Issues: 18

Number of Warnings: 10

Number of Value Errors: 9

Number of Consistency Errors: 2

Number of Format Errors: 5

Issue Log:
Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing.
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"2_4-Dihydroxybutanoic acid"
	"2_6-Dihydroxybenzoic acid"
	"3_4-Dihydroxyhydrocinnamic acid"
	"3_5-Dihydroxybenzoic acid"
	"5_6-Dihydrouracil"
	"Adenosine 3^_5^-Cyclic Monophosphate"
	"Cytidine 2^_3^-Cyclic Mono-Phos-Phate"
	"D-Glucono-1_5-Lactone"
	"Dihydro-5-methyl-2_4(1H_3H)-pyrimidinedione"
	"Guanosine 3^_5^-Cyclic Monophosphate"
	"Nepsilon_Nepsilon_Nepsilon-Trimethyllysine"
	"N_N-Dimethylglycine (or isomers)"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"2,4-Dihydroxybutanoic acid"
	"2,6-Dihydroxybenzoic acid"
	"3,4-Dihydroxyhydrocinnamic acid"
	"3,5-Dihydroxybenzoic acid"
	"5,6-Dihydrouracil"
	"Adenosine 3',5'-Cyclic Monophosphate"
	"Cytidine 2',3'-Cyclic Mono-Phos-Phate"
	"D-Glucono-1,5-Lactone"
	"Dihydro-5-methyl-2,4(1H,3H)-pyrimidinedione"
	"Guanosine 3',5'-Cyclic Monophosphate"
	"Nepsilon,Nepsilon,Nepsilon-Trimethyllysine"
	"N,N-Dimethylglycine (or isomers)"
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.