Validation Log 2025-12-14 23:29:37.149125 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN002672/mwtab/txt Study ID: ST001635 Analysis ID: AN002672 File format: txt Status: Contains Validation Issues Number of Issues: 13 Number of Warnings: 0 Number of Value Errors: 12 Number of Consistency Errors: 0 Number of Format Errors: 1 Issue Log: Error: The value, "000000", for "PROJECT_ID" in the file header must be the letters "PR" followed by 6 numbers. Ex. "PR001405". Error: The value, "24 hr", for the subsection, "TREATMENT_DOSEDURATION", in the "TREATMENT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['h', 'weeks', 'days']. Ignore this when more complicated descriptions are required. Error: The value, "3.5 KV", for the subsection, "CAPILLARY_VOLTAGE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['V', 'kV']. Ignore this when more complicated descriptions are required. Error: The value, "N2", for the subsection, "COLLISION_GAS", in the "MS" section should be one of "Nitrogen" or "Argon". Ignore this when more complicated descriptions are required. Error: The value, "45", for the subsection, "DRY_GAS_FLOW", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required. Error: The value, "325°C", for the subsection, "DRY_GAS_TEMP", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "45", for the subsection, "DESOLVATION_GAS_FLOW", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "MS_COMMENTS", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "CHROMATOGRAPHY_SUMMARY", in the "CHROMATOGRAPHY" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "8", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required. Error: The value, "6000-10000", for the subsection, "COLUMN_PRESSURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['psi', 'bar']. Ignore this when more complicated descriptions are required. Error: The value, "8", for the subsection, "INJECTION_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing.