Validation Log
2025-12-14 23:56:36.448208
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003123/mwtab/txt
Study ID:      ST001922
Analysis ID:   AN003123
File format:   txt
Status: Contains Validation Issues
Number of Issues: 28

Number of Warnings: 21

Number of Value Errors: 20

Number of Consistency Errors: 2

Number of Format Errors: 5

Issue Log:
Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section  is missing.
Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table:
	"11_12-EpETrE"
	"3_4-Dihydroxyhydrocinnamic acid"
	"3_5_5-Trimethyl-2-cyclohexen-1-one"
	"4_5-Dihydroorotic acid"
	"5^-Methylthioadenosine"
	"cis_cis-Muconic acid"
	"Fructose 1_6-bisphosphate"
	"Pyridoxal 5^-phosphate"
	"Uridine 5^-diphosphate"
	"Uridine 5^-monophosphate"
Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table:
	"11,12-EpETrE"
	"3,4-Dihydroxyhydrocinnamic acid"
	"3,5,5-Trimethyl-2-cyclohexen-1-one"
	"4,5-Dihydroorotic acid"
	"5'-Methylthioadenosine"
	"cis,cis-Muconic acid"
	"Fructose 1,6-bisphosphate"
	"Pyridoxal 5'-phosphate"
	"Uridine 5'-diphosphate"
	"Uridine 5'-monophosphate"
Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values.
Warning: The "other_id" column at position 5 in the METABOLITES table has all null values.
Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values.
Warning: The "ri" column at position 7 in the METABOLITES table has all null values.
Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values.
Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.