Validation Log
2025-12-14 23:57:54.286887
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003143/mwtab/json
Study ID:      ST001933
Analysis ID:   AN003143
File format:   json
Status: Contains Validation Issues
Number of Issues: 15

Number of Warnings: 8

Number of Value Errors: 10

Number of Consistency Errors: 0

Number of Format Errors: 5

Issue Log:
Error: The value, "23-73", in ["SUBJECT"]["AGE_OR_AGE_RANGE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required.
Error: The value, "Male and female", in ["SUBJECT"]["GENDER"] should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required.
Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing.
Warning: The "InChi key" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "inchi_key". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Ion Pairs" column at position 13 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ion". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Ion Pairs" column at position 13 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ion", and some of the values in the column do not match the expected type or format for that column. The non-matching values are:
0        230.9>143.8
1          265>136.8
2        317.9>299.9
3            376>124
4            300>210
5         298.1>99.8
6          250>113.8
7        402.2>402.1
8          225>151.8
9        476.1>235.9
10       297.2>238.2
11         309>265.9
12         225>207.9
13       476.1>457.9
14       360.2>136.8
15        282.1>83.8
16         291>273.9
17     310.20>293.00
18      268.00>70.00
19     282.00>114.00
20           265>114
21       376.1>166.1
22       362.1>314.9
23         239>151.8
24         239>221.9
25         241>205.9
26         255>219.9
27         255>237.9
28         267>113.8
29         272>117.8
30         226>153.8
31         308>126.8
32         483>135.9
33         499>151.8
34       174.9>129.8
35         226>164.8
36         259>137.8
37         271>205.8
38           273>120
39       317.1>299.9
40       318.1>164.8
41       403.1>194.8
42       301.1>283.9
43       344.1>308.9
44       404.1>386.9
45           432>415
46       481.1>327.9
47         254>235.9
48         274>120.8
49       287.8>153.8
50       315.1>161.8
51         402>248.9
52       405.1>153.8
53       446.2>292.9
54          238>56.7
55         258>104.8
56          272>78.8
57         311>129.8
58         387>233.8
59         443>245.9
60       325.1>129.8
61       451.1>297.9
62         459.2>288
63       387.1>233.9
64       401.1>247.9
65       401.1>247.9
66       435.1>281.9
67       389.1>235.8
68         209>136.8
69           251>209
70         330>209.8
71       209.9>136.8
72         237>136.8
73       239.9>136.8
74         249>136.8
75         251>136.8
76         263>136.8
77         270>136.8
78       280.9>250.9
79       307.9>136.8
80         322>126.8
81       443.1>221.9
82       193.9>136.8
83         251>136.8
84         263>136.8
85       313.9>205.8
86       638.1>559.9
87         238>193.8
88         283>136.8
89       237.8>151.8
90       237.8>151.8
91         252>193.9
92         264>219.9
93         265>136.8
94         265>136.8
95       283.8>205.8
96         284>136.8
97         284>235.9
98         298>205.8
99       313.9>235.9
100      355.1>234.9
101        208>136.8
102      223.9>205.8
103        265>136.8
104        316>151.8
105        316>193.8
106      245.9>149.8
107        286>149.8
108        338>208.9
109        222>136.8
110        222>136.8
111        286>136.8
112        373>177.8
113      398.1>279.9
114        236>136.8
115        270>149.8
116        300>281.9
117      359.1>149.8
118        385>233.9
119        401>247.9
120        415>261.9
121        435>281.9
122        429>275.9
123        250>136.8
124      443.1>151.8
125      596.1>221.9
126      596.1>233.9
127      264.1>136.8
128      357.4>136.8
129        498.1>498
130        542>541.9
131      550.1>232.9
132        599.1>599
133        583>582.9
134      278.1>136.8
135        526.1>526
136        526>526.1
137      292.1>136.8
138     306.12>136.8
139     318.13>136.8
140        583>583.1
141        583>583.1
142      332.1>136.8
143      334.2>136.8
144      360.2>136.8
145      362.2>362.1
146     376.21>376.1
147      388.2>388.1
148      412.2>412.1
149      412.2>412.1
150      414.3>414.1
151      414.3>414.1
152      436.2>436.1
153      438.2>438.1
154      440.3>440.1
155      462.2>462.1
156      464.3>464.1
157      464.3>464.1
158      466.3>466.1
159        387>233.9
160        417>221.9
161      390.3>390.1
162      404.3>404.1
163      416.1>416.1
164      416.1>416.1
165      430.3>430.1
166          383>323
167      353.2>220.1
168      518.2>220.1
169      367.2>220.1
170      381.2>220.1
171      381.2>220.1
172      397.2>220.1
173      546.2>220.1
174      395.2>220.1
175      423.3>220.1
176      451.3>220.1
177      479.3>220.1
178      507.2>220.1
179      535.2>220.1
180      561.2>220.1
181      559.2>220.1
182      559.2>220.1
183        529>231.8
184        499>231.9
185        529>231.8
186          253>236
Warning: The "PubChem CID" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "HMDB ID" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Reference RT (min)" column at position 12 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Measured RT (min)" column at position 14 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "Ionization mode" column at position 11 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "ionization_mode". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.