Validation Log
2025-12-14 23:59:23.841466
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003169/mwtab/txt
Study ID:      ST001947
Analysis ID:   AN003169
File format:   txt
Status: Contains Validation Issues
Number of Issues: 280

Number of Warnings: 270

Number of Value Errors: 277

Number of Consistency Errors: 0

Number of Format Errors: 2

Issue Log:
Error: The value, "17 day after germination", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required.
Error: The value, "250", for the subsection, "ION_SOURCE_TEMPERATURE", in the "MS" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: An empty value or a null value was detected for the subsection, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section. A legitimate value should be provided for this required subsection.
Error: The value, "1 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "80", for the subsection, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "230", for the subsection, "INJECTION_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required.
Error: The value, "280℃", for the subsection, "TRANSFERLINE_TEMPERATURE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "10 µl", for the subsection, "SAMPLE_SYRINGE_SIZE", in the "CHROMATOGRAPHY" section should be a number followed by a space with a unit (ex. "5 V") from the following list: ['μL', 'uL']. Ignore this when more complicated descriptions are required.
Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section  is missing.
Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section  is missing.
Warning: SUBJECT_SAMPLE_FACTORS entry #1 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #2 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #3 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #4 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #5 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #6 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #7 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #8 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #9 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #10 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #11 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #12 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #13 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #14 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #15 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #16 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #17 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #18 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #19 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #20 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #21 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #22 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #23 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #24 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #25 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #26 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #27 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #28 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #29 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #30 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #31 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #32 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #33 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #34 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #35 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #36 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #37 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #38 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #39 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #40 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #41 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #42 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #43 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #44 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #45 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #46 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #47 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #48 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #49 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #50 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #51 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #52 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #53 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #54 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #55 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #56 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #57 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #58 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #59 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #60 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #61 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #62 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #63 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #64 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #65 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #66 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #67 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #68 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #69 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #70 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #71 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #72 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #73 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #74 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #75 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #76 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #77 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #78 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #79 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #80 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #81 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #82 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #83 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #84 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #85 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #86 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #87 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #88 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #89 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #90 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #91 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #92 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #93 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #94 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #95 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #96 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #97 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #98 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #99 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #100 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #101 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #102 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #103 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #104 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #105 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #106 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #107 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #108 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #109 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #110 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #111 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #112 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #113 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #114 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #115 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #116 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #117 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #118 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #119 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #120 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #121 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #122 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #123 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #124 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #125 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #126 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #127 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #128 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #129 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #130 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #131 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #132 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #133 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #134 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #135 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #136 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #137 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #138 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #139 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #140 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #141 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #142 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #143 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #144 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #145 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #146 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #147 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #148 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #149 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #150 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #151 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #152 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #153 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #154 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #155 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #156 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #157 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #158 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #159 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #160 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #161 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #162 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #163 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #164 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #165 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #166 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #167 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #168 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #169 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #170 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #171 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #172 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #173 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #174 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #175 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #176 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #177 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #178 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #179 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #180 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #181 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #182 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #183 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #184 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #185 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #186 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #187 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #188 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #189 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #190 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #191 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #192 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #193 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #194 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #195 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #196 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #197 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #198 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #199 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #200 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #201 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #202 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #203 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #204 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #205 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #206 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #207 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #208 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #209 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #210 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #211 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #212 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #213 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #214 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #215 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #216 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #217 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #218 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #219 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #220 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #221 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #222 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #223 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #224 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #225 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #226 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #227 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #228 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #229 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #230 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #231 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #232 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #233 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #234 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #235 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #236 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #237 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #238 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #239 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #240 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #241 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #242 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #243 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #244 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #245 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #246 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #247 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #248 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #249 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #250 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #251 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #252 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #253 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #254 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #255 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #256 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #257 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #258 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #259 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #260 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #261 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #262 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #263 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #264 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: SUBJECT_SAMPLE_FACTORS entry #265 has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The "quantified m/z" column at position 3 in the METABOLITES table, matches a standard column name, "moverz_quant". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "PubChem ID" column at position 4 in the METABOLITES table, matches a standard column name, "pubchem_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "KEGG ID" column at position 5 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "retention index" column at position 2 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column "retention index" was found in the METABOLITES table, but this column implies that another column, "retention_index_type", should also exist, and that column was not found.