Validation Log
2025-12-15 00:03:11.599830
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003244/mwtab/json
Study ID:      ST001990
Analysis ID:   AN003244
File format:   json
Status: Contains Validation Issues
Number of Issues: 41

Number of Warnings: 35

Number of Value Errors: 41

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: An empty value or a null value was detected in ["SUBJECT_SAMPLE_FACTORS"][33]["Additional sample data"]["RAW_FILE_NAME"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: An empty value or a null value was detected in ["SUBJECT_SAMPLE_FACTORS"][34]["Additional sample data"]["RAW_FILE_NAME"]. Either a legitimate value should be provided for this key, or it should be removed altogether.
Error: The value, "150 ºC", in ["MS"]["SOURCE_TEMPERATURE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "550 L/hr.", in ["MS"]["DESOLVATION_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "0.5 mL·min-1", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "35 ºC", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][15] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][16] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][17] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][18] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][19] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][20] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][21] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][22] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][23] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][24] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][25] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][26] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][27] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][28] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][29] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][30] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][31] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][32] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][33] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][34] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
	"RAW_FILE_NAME"