Validation Log 2025-12-15 00:16:36.723811 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003408/mwtab/txt Study ID: ST002088 Analysis ID: AN003408 File format: txt Status: Contains Validation Issues Number of Issues: 18 Number of Warnings: 9 Number of Value Errors: 10 Number of Consistency Errors: 2 Number of Format Errors: 5 Issue Log: Error: The value, "40-80", for the subsection, "AGE_OR_AGE_RANGE", in the "SUBJECT" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['weeks', 'days', 'months', 'years']. Ignore this when more complicated descriptions are required. Error: The value, "Male and female", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: The required property, "FLOW_GRADIENT", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "FLOW_RATE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "COLUMN_TEMPERATURE", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_A", in the "CHROMATOGRAPHY" section is missing. Error: The required property, "SOLVENT_B", in the "CHROMATOGRAPHY" section is missing. Error: The following metabolites in the, MS_METABOLITE_DATA table were not found in the METABOLITES table: "12_13-DiHOME" "1_2_3-benzenetriol sulfate (2)" "1_3_7-trimethylurate" "1_3-dimethylurate" "1_5-anhydroglucitol (1_5-AG)" "1_7-dimethylurate" "2_2^-methylenebis(6-tert-butyl-p-cresol)" "2_3-dihydroxy-2-methylbutyrate" "2_3-dihydroxy-5-methylthio-4-pentenoate (DMTPA)*" "2_3-diphosphoglycerate" "2_4-di-tert-butylphenol" "(2_4 or 2_5)-dimethylphenol sulfate" "2_6-dihydroxybenzoic acid" "2_8-quinolinediol sulfate" "2^-deoxyuridine" "2^-O-methyluridine" "3_7-dimethylurate" "3beta_7alpha-dihydroxy-5-cholestenoate" "3-bromo-5-chloro-2_6-dihydroxybenzoic acid*" "5_6-dihydrothymine" "5_6-dihydrouridine" "5alpha-androstan-3alpha_17beta-diol 17-glucuronide" "5alpha-androstan-3alpha_17beta-diol disulfate" "5alpha-androstan-3alpha_17beta-diol monosulfate (1)" "5alpha-androstan-3alpha_17beta-diol monosulfate (2)" "5alpha-androstan-3beta_17alpha-diol disulfate" "5alpha-androstan-3beta_17beta-diol disulfate" "5alpha-androstan-3beta_17beta-diol monosulfate (2)" "5alpha-pregnan-3beta_20alpha-diol disulfate" "5alpha-pregnan-3beta_20alpha-diol monosulfate (2)" "5alpha-pregnan-3beta_20beta-diol monosulfate (1)" "9_10-DiHOME" "adenosine 3^_5^-cyclic monophosphate (cAMP)" "androstenediol (3alpha_ 17alpha) monosulfate (2)" "androstenediol (3alpha_ 17alpha) monosulfate (3)" "androstenediol (3beta_17beta) disulfate (1)" "androstenediol (3beta_17beta) disulfate (2)" "androstenediol (3beta_17beta) monosulfate (1)" "androstenediol (3beta_17beta) monosulfate (2)" "bilirubin (E_E)*" "branched-chain_ straight-chain_ or cyclopropyl 10:1 fatty acid (1)*" "branched-chain_ straight-chain_ or cyclopropyl 12:1 fatty acid*" "fibrinopeptide A_ des-ala(1)*" "fibrinopeptide A_ phosphono-ser(3)*" "N2_N5-diacetylornithine" "N_N_N-trimethyl-alanylproline betaine (TMAP)" "N_O-didesmethylvenlafaxine glucuronide" "trans-3_4-methyleneheptanoate" "trans-3_4-methyleneheptanoylcarnitine" Error: The following metabolites in the METABOLITES table were not found in the MS_METABOLITE_DATA table: "12,13-DiHOME" "1,2,3-benzenetriol sulfate (2)" "1,3,7-trimethylurate" "1,3-dimethylurate" "1,5-anhydroglucitol (1,5-AG)" "1,7-dimethylurate" "2,2'-methylenebis(6-tert-butyl-p-cresol)" "2,3-dihydroxy-2-methylbutyrate" "2,3-dihydroxy-5-methylthio-4-pentenoate (DMTPA)*" "2,3-diphosphoglycerate" "2,4-di-tert-butylphenol" "(2,4 or 2,5)-dimethylphenol sulfate" "2,6-dihydroxybenzoic acid" "2,8-quinolinediol sulfate" "2'-deoxyuridine" "2'-O-methyluridine" "3,7-dimethylurate" "3beta,7alpha-dihydroxy-5-cholestenoate" "3-bromo-5-chloro-2,6-dihydroxybenzoic acid*" "5,6-dihydrothymine" "5,6-dihydrouridine" "5alpha-androstan-3alpha,17beta-diol 17-glucuronide" "5alpha-androstan-3alpha,17beta-diol disulfate" "5alpha-androstan-3alpha,17beta-diol monosulfate (1)" "5alpha-androstan-3alpha,17beta-diol monosulfate (2)" "5alpha-androstan-3beta,17alpha-diol disulfate" "5alpha-androstan-3beta,17beta-diol disulfate" "5alpha-androstan-3beta,17beta-diol monosulfate (2)" "5alpha-pregnan-3beta,20alpha-diol disulfate" "5alpha-pregnan-3beta,20alpha-diol monosulfate (2)" "5alpha-pregnan-3beta,20beta-diol monosulfate (1)" "9,10-DiHOME" "adenosine 3',5'-cyclic monophosphate (cAMP)" "androstenediol (3alpha, 17alpha) monosulfate (2)" "androstenediol (3alpha, 17alpha) monosulfate (3)" "androstenediol (3beta,17beta) disulfate (1)" "androstenediol (3beta,17beta) disulfate (2)" "androstenediol (3beta,17beta) monosulfate (1)" "androstenediol (3beta,17beta) monosulfate (2)" "bilirubin (E,E)*" "branched-chain, straight-chain, or cyclopropyl 10:1 fatty acid (1)*" "branched-chain, straight-chain, or cyclopropyl 12:1 fatty acid*" "fibrinopeptide A, des-ala(1)*" "fibrinopeptide A, phosphono-ser(3)*" "N2,N5-diacetylornithine" "N,N,N-trimethyl-alanylproline betaine (TMAP)" "N,O-didesmethylvenlafaxine glucuronide" "trans-3,4-methyleneheptanoate" "trans-3,4-methyleneheptanoylcarnitine" Warning: The "ri" column at position 7 in the METABOLITES table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "ri_type" column at position 8 in the METABOLITES table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column. Warning: The "inchi_key" column at position 3 in the METABOLITES table has all null values. Warning: The "other_id" column at position 5 in the METABOLITES table has all null values. Warning: The "other_id_type" column at position 6 in the METABOLITES table has all null values. Warning: The "ri" column at position 7 in the METABOLITES table has all null values. Warning: The "ri_type" column at position 8 in the METABOLITES table has all null values. Warning: The "moverz_quant" column at position 9 in the METABOLITES table has all null values.