Validation Log
2025-12-15 00:19:55.671754
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003437/mwtab/json
Study ID:      ST002103
Analysis ID:   AN003437
File format:   json
Status: Contains Validation Issues
Number of Issues: 85

Number of Warnings: 75

Number of Value Errors: 85

Number of Consistency Errors: 0

Number of Format Errors: 0

Issue Log:
Error: An empty value or a null value was detected in ["SUBJECT_SAMPLE_FACTORS"][0]["Sample ID"]. A legitimate value should be provided for this required key.
Error: An empty value or a null value was detected in ["TREATMENT"]["TREATMENT_SUMMARY"]. A legitimate value should be provided for this required key.
Error: The value, "N2", in ["MS"]["COLLISION_GAS"] should be one of "Nitrogen" or "Argon". Ignore this when more complicated descriptions are required.
Error: The value, "55", in ["MS"]["DRY_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "400°C", in ["MS"]["DRY_GAS_TEMP"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "3.5 KV", in ["MS"]["SPRAY_VOLTAGE"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['kV']. Ignore this when more complicated descriptions are required.
Error: The value, "55", in ["MS"]["DESOLVATION_GAS_FLOW"] should be a number followed by a space with a unit (ex. "5 V") from the following list: ['L/hr', 'L/min']. Ignore this when more complicated descriptions are required.
Error: The value, "0.4 ml/min", in ["CHROMATOGRAPHY"]["FLOW_RATE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required.
Error: The value, "50", in ["CHROMATOGRAPHY"]["COLUMN_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C']. Ignore this when more complicated descriptions are required.
Error: The value, "8", in ["CHROMATOGRAPHY"]["INJECTION_TEMPERATURE"] should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['°C', 'C'] or "room temperature". Ignore this when more complicated descriptions are required.
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][0] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][1] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][2] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][3] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][4] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][5] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][6] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][7] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][8] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][9] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][10] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][11] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][12] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][13] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][14] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][15] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][16] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][17] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][18] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][19] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][20] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][21] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][22] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][23] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][24] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][25] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][26] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][27] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][28] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][29] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][30] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][31] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][32] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][33] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][34] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][35] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][36] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][37] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][38] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][39] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][40] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][41] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][42] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][43] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][44] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][45] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][46] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][47] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][48] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][49] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][50] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][51] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][52] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][53] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][54] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][55] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][56] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][57] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][58] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][59] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][60] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][61] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][62] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][63] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][64] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][65] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][66] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][67] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][68] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][69] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][70] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][71] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][72] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][73] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"
Warning: The SSF at ["SUBJECT_SAMPLE_FACTORS"][74] has the following duplicate keys in its Additional sample data:
	"RAW_FILE_NAME"