Validation Log 2025-12-15 00:19:59.841858 mwtab Python Library Version: 2.0.0 Source: https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003439/mwtab/txt Study ID: ST002104 Analysis ID: AN003439 File format: txt Status: Contains Validation Issues Number of Issues: 14 Number of Warnings: 7 Number of Value Errors: 14 Number of Consistency Errors: 0 Number of Format Errors: 0 Issue Log: Error: An empty value or a null value was detected for the subsection, "NUM_MALES", in the "STUDY" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: An empty value or a null value was detected for the subsection, "NUM_FEMALES", in the "STUDY" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "Not applicable", for the subsection, "GENDER", in the "SUBJECT" section should be one of "Male", "Female", "Male, Female", "Hermaphrodite", or "N/A". Ignore this when more complicated descriptions are required. Error: An empty value or a null value was detected for the subsection, "COLLISION_ENERGY", in the "MS" section. Either a legitimate value should be provided for this subsection, or it should be removed altogether. Error: The value, "NA", for the subsection, "COLLISION_GAS", in the "MS" section should be one of "Nitrogen" or "Argon". Ignore this when more complicated descriptions are required. Error: The value, "0.3 ml/min", for the subsection, "FLOW_RATE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['mL/min', 'uL/min', 'μL/min']. Ignore this when more complicated descriptions are required. Error: The value, "60 bar at starting conditions", for the subsection, "COLUMN_PRESSURE", in the "CHROMATOGRAPHY" section should be a number or range (ex. "5-6") followed by a space with a unit (ex. "5 V") from the following list: ['psi', 'bar']. Ignore this when more complicated descriptions are required. Warning: The "InchiKEY" column at position 6 in the METABOLITES table, matches a standard column name, "inchi_key". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGGid" column at position 4 in the METABOLITES table, matches a standard column name, "kegg_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "KEGGid" column at position 4 in the METABOLITES table, matches a standard column name, "kegg_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 0 0 16 0 17 0 21 0 22 0 27 0 30 0 33 0 36 0 47 0 49 0 51 0 54 0 55 0 56 0 62 0 67 0 68 0 69 0 73 0 75 0 77 0 82 0 85 0 89 0 91 0 92 0 93 0 96 0 97 0 98 0 101 0 102 0 103 0 104 0 105 0 114 0 115 0 117 0 119 0 122 0 123 0 124 0 125 0 129 0 137 0 140 0 141 0 142 0 143 0 144 0 145 0 147 0 148 0 149 0 150 0 153 0 157 0 158 0 161 0 162 0 163 0 165 0 170 0 171 0 174 0 176 0 178 0 179 0 181 0 183 0 184 0 187 0 188 0 191 0 193 0 194 0 195 0 197 0 198 0 199 0 200 0 201 0 202 0 203 0 204 0 207 0 209 0 210 0 211 0 212 0 213 0 214 0 215 0 216 0 217 0 218 0 219 0 221 0 225 0 226 0 227 0 231 0 233 0 234 0 238 0 239 0 240 0 242 0 243 0 244 0 245 0 246 0 250 0 251 0 252 0 253 0 254 0 255 0 256 0 257 0 259 0 260 0 261 0 263 0 264 0 265 0 266 0 268 0 269 0 270 0 271 0 272 0 274 0 276 0 277 0 278 0 280 0 281 0 282 0 283 0 285 0 Warning: The "HMDBID" column at position 7 in the METABOLITES table, matches a standard column name, "hmdb_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "HMDBID" column at position 7 in the METABOLITES table, matches a standard column name, "hmdb_id", and some of the values in the column do not match the expected type or format for that column. The non-matching values are: 5 0 11 0 12 0 18 0 22 0 27 0 31 0 36 0 39 0 49 0 54 0 56 0 62 0 66 0 68 0 69 0 70 0 75 0 81 0 85 0 88 0 89 0 94 0 96 0 97 0 98 0 102 0 103 0 115 0 117 0 121 0 123 0 129 0 132 0 136 0 137 0 138 0 140 0 142 0 143 0 147 0 149 0 153 0 154 0 161 0 162 0 174 0 177 0 178 0 179 0 185 0 192 0 194 0 195 0 199 0 200 0 202 0 204 0 207 0 208 0 209 0 210 0 212 0 213 0 214 0 216 0 217 0 222 0 225 0 227 0 228 0 231 0 233 0 234 0 236 0 238 0 240 0 244 0 245 0 246 0 248 0 251 0 253 0 254 0 256 0 258 0 261 0 263 0 267 0 270 0 271 0 272 0 273 0 274 0 277 0 278 0 279 0 280 0 281 0 282 0 283 0 284 0 285 0 Warning: The "Lmid" column at position 5 in the METABOLITES table, matches a standard column name, "lm_id". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name. Warning: The "retention time" column at position 2 in the METABOLITES table, matches a standard column name, "retention_time". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.