Validation Log
2025-12-15 00:21:55.377069
mwtab Python Library Version: 2.0.0
Source:        https://www.metabolomicsworkbench.org/rest/study/analysis_id/AN003479/mwtab/json
Study ID:      ST002126
Analysis ID:   AN003479
File format:   json
Status: Contains Validation Issues
Number of Issues: 20

Number of Warnings: 12

Number of Value Errors: 11

Number of Consistency Errors: 2

Number of Format Errors: 5

Issue Log:
Error: The required property, "FLOW_GRADIENT", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "FLOW_RATE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "COLUMN_TEMPERATURE", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_A", in ["CHROMATOGRAPHY"] is missing.
Error: The required property, "SOLVENT_B", in ["CHROMATOGRAPHY"] is missing.
Error: The following metabolites in the, ["MS_METABOLITE_DATA"]["Data"] table were not found in the ["MS_METABOLITE_DATA"]["Metabolites"] table:
	"[13C_ 15N]Alanine_ 2TBDMS"
	"[13C_ 15N]Aspartic acid_ 3TBDMS"
	"[13C_ 15N]Glutamic acid_ 3TBDMS"
	"[13C_ 15N]Glycine_ 2TBDMS"
	"[13C_ 15N]Histidine_ 3TBDMS"
	"[13C_ 15N]Isoleucine_ 2TBDMS"
	"[13C_ 15N]Leucine_ 2TBDMS"
	"[13C_ 15N]Lysine_ 3TBDMS"
	"[13C_ 15N]Methionine_ 2TBDMS"
	"[13C_ 15N]Phenylalanine_ 2TBDMS"
	"[13C_ 15N]Proline_ 2TBDMS"
	"[13C_ 15N]Serine_ 3TBDMS"
	"[13C_ 15N]Threonine_ 3TBDMS"
	"[13C_ 15N]Tyrosine_ 3TBDMS"
	"[13C_ 15N]Valine_ 2TBDMS"
	"Alanine_ 2TBDMS"
	"Aspartic acid_ 3TBDMS"
	"Glutamic acid_ 3TBDMS"
	"Glutamine_ 3TBDMS"
	"Glycine_ 2TBDMS"
	"Histidine_ 3TBDMS"
	"Hydroxyproline_ (E)-_ 3TBDMS"
	"Isoleucine_ 2TBDMS"
	"L-Cysteine_ 3TBDMS"
	"Leucine_ 2TBDMS"
	"Lysine_ 3TBDMS"
	"Methionine_ 2TBDMS"
	"Phenylalanine_ 2TBDMS"
	"Proline_ 2TBDMS"
	"Serine_ 3TBDMS"
	"Threonine_ 3TBDMS"
	"Tyrosine_ 3TBDMS"
	"Valine_ 2TBDMS"
Error: The following metabolites in the ["MS_METABOLITE_DATA"]["Metabolites"] table were not found in the ["MS_METABOLITE_DATA"]["Data"] table:
	"[13C, 15N]Alanine, 2TBDMS"
	"[13C, 15N]Aspartic acid, 3TBDMS"
	"[13C, 15N]Glutamic acid, 3TBDMS"
	"[13C, 15N]Glycine, 2TBDMS"
	"[13C, 15N]Histidine, 3TBDMS"
	"[13C, 15N]Isoleucine, 2TBDMS"
	"[13C, 15N]Leucine, 2TBDMS"
	"[13C, 15N]Lysine, 3TBDMS"
	"[13C, 15N]Methionine, 2TBDMS"
	"[13C, 15N]Phenylalanine, 2TBDMS"
	"[13C, 15N]Proline, 2TBDMS"
	"[13C, 15N]Serine, 3TBDMS"
	"[13C, 15N]Threonine, 3TBDMS"
	"[13C, 15N]Tyrosine, 3TBDMS"
	"[13C, 15N]Valine, 2TBDMS"
	"Alanine, 2TBDMS"
	"Aspartic acid, 3TBDMS"
	"Glutamic acid, 3TBDMS"
	"Glutamine, 3TBDMS"
	"Glycine, 2TBDMS"
	"Histidine, 3TBDMS"
	"Hydroxyproline, (E)-, 3TBDMS"
	"Isoleucine, 2TBDMS"
	"L-Cysteine, 3TBDMS"
	"Leucine, 2TBDMS"
	"Lysine, 3TBDMS"
	"Methionine, 2TBDMS"
	"Phenylalanine, 2TBDMS"
	"Proline, 2TBDMS"
	"Serine, 3TBDMS"
	"Threonine, 3TBDMS"
	"Tyrosine, 3TBDMS"
	"Valine, 2TBDMS"
Warning: The "ri" column at position 7 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table, matches a standard column name, "retention_index_type". If this match was not in error, the column should be renamed to the standard name or a name that doesn't resemble the standard name.
Warning: The column pair, "ri" and "ri_type", in the METABOLITES table should have data in the same rows, but at least one row has data in one column and nothing in the other.
Warning: The standard column, "other_id", was found in the METABOLITES table as "other_id". If this column contains database IDs for standard databases such as KEGG, PubChem, HMDB, etc., it is recommended to make individual columns for these and not lump them together into a less descriptive "other_id" column.
Error: Column(s) with no name were found in the ["MS_METABOLITE_DATA"]["Metabolites"] table.
Warning: The "pubchem_id" column at position 2 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "inchi_key" column at position 3 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "kegg_id" column at position 4 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id" column at position 5 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "other_id_type" column at position 6 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "ri_type" column at position 8 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "moverz_quant" column at position 9 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.
Warning: The "" column at position 10 in the ["MS_METABOLITE_DATA"]["Metabolites"] table has all null values.